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arXiv:1102.4642

BEC phase diagram of a $^{87}$Rb trapped gas in terms of macroscopic thermodynamic parameters

Vı́ctor Romero-Rochı́n, R. F. Shiozaki, M. A. Caracanhas, E. A. L. Henn, K. M. F. Magalhães, G. Roati, Vanderlei Salvador Bagnato

Published Feb 23, 2011• 0 citations
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Abstract

We measure the phase diagram of a $^{87}$Rb Bose gas in a harmonic trap in terms of macroscopic parameters obtained from the spatial distribution of atoms. Considering the relevant variables as size of the cloud ${\cal V}$, number of atoms $N$ and temperature $T$, a novel parameter $Π= Π(N,{\cal V},T)$ is introduced to characterize the overall pressure of the system. We construct the phase diagram ($Π$ vs $T$) identifying new features related to Bose-Einstein condensation (BEC) transition in a trapped gas. A thermodynamic description of the phase transition based on purely macroscopic parameters, provide us with properties that do not need the local density approximation. An unexpected consequence of this analysis is the suggestion that BEC appears as a continuous third-order phase transition instead of being a second-order one.

DOI
10.48550/arxiv.1102.4642

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BEC phase diagram of a 87^{87}87Rb trapped gas in terms of macroscopic thermodynamic parameters
We measure the phase diagram of a 87^{87}87Rb Bose gas in a harmonic trap in terms of macroscopic parameters obtained from the spatial distribution of atoms. Considering the relevant variables as size of the cloud V{\cal V}V, number of atoms NNN and temperature TTT, a novel parameter Π=Π(N,V,T)Π= Π(N,{\cal V},T)Π=Π(N,V,T) is introduced to characterize the overall pressure of the system. We construct the phase diagram (ΠΠΠ vs TTT) identifying new features related to Bose-Einstein condensation (BEC) transition in a trapped gas. A thermodynamic description of the phase transition based on purely macroscopic parameters, provide us with properties that do not need the local density approximation. An unexpected consequence of this analysis is the suggestion that BEC appears as a continuous third-order phase transition instead of being a second-order one.
To overcome the difficulties in defining pressure for a gas confined in an inhomogeneous trap, we define single macroscopic parameters that behave like pressure and volume. We measure the phase diagram of a 87{}^{87}87Rb Bose gas in a harmonic trap in terms of those macroscopic parameters obtained from the spatial distribution of atoms. Considering the relevant variables such as the trap potential $\mathcal{V}={({\ensuremath{\omega}}_{x}{\ensuremath{\omega}}_{y}{\ensuremath{\omega}}_{z})}^{\ensuremath{-}1}$, number of atoms NNN, and temperature TTT, a parameter $\ensuremath{\Pi}=\ensuremath{\Pi}(N,\mathcal{V},T)$ is introduced to characterize the overall macroscopic pressure of the system. We construct the phase diagram ($\ensuremath{\Pi}$ vs TTT) identifying the main features related to the Bose-Einstein condensation (BEC) transition in a trapped gas. A thermodynamic description of the phase transition based on purely macroscopic parameters provides us with a description that does not need the local-density approximation. This procedure can be used to explore different aspects related to BEC such as the nature of the phase transition in a trapped gas.
We apply the global thermodynamic variables approach to experimentally determine the isothermal compressibility parameter ${\ensuremath{\kappa}}_{T}$ of a trapped Bose gas across the phase transition. We demonstrate the behavior of ${\ensuremath{\kappa}}_{T}$ around the critical pressure, revealing the second-order nature of the phase transition. Compressibility is the most important susceptibility to characterize the system. The use of global variables shows advantages with respect to the usual local density approximation method and can be applied to a broad range of situations.
Abstract The critical properties displayed by an ideal 2D Bose gas trapped in a harmonic potential are determined and characterized in an exact numerical fashion. Beyond thermodynamics, addressed in terms of the global pressure and volume which are the appropriate variables of a fluid confined in a non-uniform harmonic potential, the density-density correlation function is also calculated and the corresponding correlation length is found. Evaluation of all these quantities as Bose–Einstein condensation (BEC) is approached manifest its critical continuous phase transition character. The divergence of the correlation length as the critical temperature is reached, unveils the expected spatial scale invariance proper of a critical transition. The logarithmic singularities of this transition are traced back to the non-analytic behavior of the thermodynamic variables at vanishing chemical potential, which is the onset of BEC. The critical exponents associated with the ideal BEC transition in the 2D inhomogeneous fluid reveals its own universality class.
Ultra cold quantum gas is a convenient system to study fundamental questions of modern physics, such as phase transitions and critical phenomena. This master thesis is devoted to experimental investigation of the thermodynamics susceptibilities, such as the isothermal compressibility and the thermal expansion coefficient of a trapped Bose-Einstein condensate (BEC) of 87Rb atoms. The critical phenomena and the critical exponents across the transition can explain the behavior of the isothermal compressibility and the thermal expansion coefficient near the critical temperature TC. By employing the developed formalism of global thermodynamics variables, we carry out a statistical treatment of Bose gas in a 3D harmonic potential. After that, comparison of obtained results reveals the most appropriate state variables describing the system, namely volume and pressure parameter V and Π respectively. The both are related with the confining frequencies and BEC density distribution. We apply this approach to define the set of new thermodynamic variables of BEC, and also to construct the isobaric phase diagram V T. Its allows us to extract the compressibility κT and the thermal expansion coefficient βΠ. The behavior of the isothermal compressibility corresponds to the second-order phase transition, while the thermal expansion coefficient around the critical point behaves as β ∼ tr-α, where tr is reduced temperature of the system and α is the critical exponent on the basic of these. Results we have obtained the critical exponent α = 0.15±0.09, which allows us to determine the system dimensionality by means of the scaling theory, relating the critical exponents with the dimensionality. As a result, we found out that the dimensionality of the system to be d ∼ 3, one is in agreement with the real dimension of the system.
Evading the Mermin–Wagner–Hohenberg no-go theorem and revisiting with rigor the ideal Bose gas confined in a square box, we explore a discrete phase transition in two spatial dimensions. Through both analytic and numerical methods, we verify that thermodynamic instability emerges if the number of particles is sufficiently yet finitely large: specifically, N ⩾ 35131 . The instability implies that the isobar of the gas zigzags on the temperature–volume plane, featuring supercooling and superheating phenomena. The Bose–Einstein condensation can then persist from absolute zero to the superheating temperature. Without necessarily taking the large N limit, under a constant pressure condition, the condensation takes place discretely both in the momentum and in the position spaces. Our result is applicable to a harmonic trap. We assert that experimentally observed Bose–Einstein condensations of harmonically trapped atomic gases are a first-order phase transition that involves a discrete change of the density at the center of the trap.
We consider a Bose gas confined by a harmonic potential. We define an appropriate thermodynamic limit and analyze the properties of the phases and phase transition in this limit. Critical properties in the presence of the potential are found to be different from, though simply related to, those in the usual translationally invariant case. We argue that the properties of magnetically trapped rubidium and sodium gases (in which Bose-Einstein condensation has recently been observed) are well approximated by our thermodynamic limit except in a narrow window of temperature around the critical temperature. We also consider the effect of the confining potential on the non-equilibrium dynamics following a rapid quench to the ordered side and give a scaling description of the late-time universal dynamics.