Entanglement is nowadays considered as a key quantity for the understanding of correlations, transport properties, and phase transitions in composite quantum systems, and thus receives interest beyond the engineered applications in the focus of quantum information science. We review recent experimental and theoretical progress in the study of quantum correlations under that wider perspective, with an emphasis on rigorous definitions of the entanglement of identical particles, and on entanglement studies in atoms and molecules.
Entanglement is nowadays considered as a key quantity for the understanding of correlations, transport properties, and phase transitions in composite quantum systems, and thus receives interest beyond the engineered applications in the focus of quantum information science. We review recent experimental and theoretical progress in the study of quantum correlations under that wider perspective, with an emphasis on rigorous definitions of the entanglement of identical particles, and on entanglement studies in atoms and molecules.
Abstract The detection and certification of entanglement and quantum correlations in materials is of fundamental and far‐reaching importance, and has seen significant recent progress. It impacts both the understanding of the basic science of quantum many‐body phenomena as well as the identification of systems suitable for novel technologies. Frameworks suitable to condensed matter that connect measurements to entanglement and coherence have been developed in the context of quantum information theory. These take the form of entanglement witnesses and quantum correlation measures. The underlying theory of these quantities, their relation to condensed matter experimental techniques, and their application to real materials are comprehensively reviewed. In addition, their usage in, e.g., protocols, the relative advantages and disadvantages of witnesses and measures, and future prospects in, e.g., correlated electrons, entanglement dynamics, and entangled spectroscopic probes, are presented. Consideration is given to the interdisciplinary nature of this emerging research and substantial ongoing progress by providing an accessible and practical treatment from fundamentals to application. Particular emphasis is placed on quantities accessible to collective measurements, including by susceptibility and spectroscopic techniques. This includes the magnetic susceptibility witness, one‐tangle, concurrence and two‐tangle, two‐site quantum discord, and quantum coherence measures such as the quantum Fisher information.
In the past decades, rapid advances in the experimental control of quantum systems have opened up unparalleled capabilities of engineering exotic quantum states. Nowadays, we may consider ourselves witnesses of a second quantum revolution as strongly correlated quantum matter is regularly created, on a daily basis, within the most diverse platforms, e.g. arrays of Rydberg atoms, ultra-cold atoms in optical lattices, superconducting qubits, trapped ions, and quantum dots. In this era, dubbed Noisy-Intermediate Scale Quantum (NISQ) era, the effort in pursuing research for realizing quantum technologies with practical purposes, such as quantum computing, simulations, communication and metrology, has greatly accelerated, and we are just starting to experience the immense progress that could be achieved. The remarkable breakthrough we are facing builds upon seminal theoretical and experimental advances in quantum physics. The key achievements in atomic, molecular, and optical (AMO) physics have opened up the possibility of controlling, trapping, and measuring single atoms, one by one, with high accuracy and reliability. In parallel, from a theoretical point of view, the study of quantum entanglement and correlations has bridged AMO physics and quantum information with crucial proposals for the realization of universal quantum computers. In this context, entanglement has emerged as one of the key tools to characterize and to exploit quantum many-body systems for quantum information purposes. We will study quantum entanglement in several scenarios to investigate and probe complex quantum many-body systems. We will consider examples ranging from generic mixed states in equilibrium to out-of-equilibrium dynamics, with and without dissipation, and topologically non-trivial systems. The leitmotif of this work will be how entanglement and correlations can be exploited to characterize the many-body quantum state describing a physical system and how entanglement can be detected in an experimentally efficient manner.
The study of entanglement in systems composed of identical particles raises interesting challenges with far-reaching implications in both, our fundamental understanding of the physics of composite quantum systems, and our capability of exploiting quantum indistinguishability as a resource in quantum information theory. Impressive theoretical and experimental advances have been made in the last decades that bring us closer to a deeper comprehension and to a better control of entanglement. Yet, when it involves composites of indistinguishable quantum systems, the very meaning of entanglement, and hence its characterization, still finds controversy and lacks a widely accepted definition. The aim of the present paper is to introduce, within an accessible and self-contained exposition, the basic ideas behind one of the approaches advanced towards the construction of a coherent definition of entanglement in systems of indistinguishable particles, with focus on fermionic systems. We also inquire whether the corresponding tools developed for studying entanglement in identical-fermion systems can be exploited when analysing correlations in distinguishable-party systems, in which the complete information of the individual parts is not available. Further, we open the discussion on the broader problem of constructing a suitable framework that accommodates entanglement in the presence of generalized statistics. This article is part of the theme issue 'Identity, individuality and indistinguishability in physics and mathematics'.
Abstract Quantum information theory is built upon the realisation that quantum resources like coherence and entanglement can be exploited for novel or enhanced ways of transmitting and manipulating information, such as quantum cryptography, teleportation, and quantum computing. We now know that there is potentially much more than entanglement behind the power of quantum information processing. There exist more general forms of non-classical correlations, stemming from fundamental principles such as the necessary disturbance induced by a local measurement, or the persistence of quantum coherence in all possible local bases. These signatures can be identified and are resilient in almost all quantum states, and have been linked to the enhanced performance of certain quantum protocols over classical ones in noisy conditions. Their presence represents, among other things, one of the most essential manifestations of quantumness in cooperative systems, from the subatomic to the macroscopic domain. In this work we give an overview of the current quest for a proper understanding and characterisation of the frontier between classical and quantum correlations (QCs) in composite states. We focus on various approaches to define and quantify general QCs, based on different yet interlinked physical perspectives, and comment on the operational significance of the ensuing measures for quantum technology tasks such as information encoding, distribution, discrimination and metrology. We then provide a broader outlook of a few applications in which quantumness beyond entanglement looks fit to play a key role.
Quantum information, a field in which great advances have been made in the past decades, now presents opportunities for advanced chemistry. One roadblock to progress, especially for experimental chemical science, is that new concepts and technical definitions need to be learned. In this paper, we review some basic, but sometimes misunderstood, concepts of quantum information based on the mathematical formulation of quantum mechanics that will be useful for chemists interested in discovering ways that chemistry can contribute to the quantum information field. We cover topics including qubits and their density matrix formalism, quantum measurement as a quantum operation, information theory, and entanglement. We focus on the difference between the concepts in the quantum context and the classic context. We also discuss the relation and distinction among entanglement, correlation, and coherence. We aim to clarify the rigorous definition of these concepts and then indicate some examples in physical chemistry.
The enormous experimental progress in atomic, molecular and optical (AMO) physics during the last decades allows us nowadays to isolate single, a few or even many-body ensembles of microscopic particles, and to manipulate their quantum properties at a level of precision, which still seemed unthinkable some years ago. This versatile set of tools has enabled the development of the well-established concept of engineering of many-body Hamiltonians in various physical platforms. These available tools, however, can also be harnessed to extend the scenario of Hamiltonian engineering to a more general Liouvillian setting, which in addition to coherent dynamics also includes controlled dissipation in many-body quantum systems. Here, we review recent theoretical and experimental progress in different directions along these lines, with a particular focus on physical realizations with systems of atoms and ions. This comprises digital quantum simulations in a general open system setting, as well as engineering and understanding new classes of systems far away from thermodynamic equilibrium.