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arXiv:1012.0236

The thermodynamic origin of the Contact and its relation to the gap in the BEC-BCS crossover

Vı́ctor Romero-Rochı́n

Published Dec 1, 2010• 0 citations
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Abstract

As can be inferred from present experiments in ultracold gases, the scattering length is a quantity that determines the thermodynamic state of the gas. As such, there exists a conjugate thermodynamic to it. Here, we show that the recently introduced "contact" is the conjugate of the inverse of the scattering length. We find that this identification allows for a derivation of essentially all the known results regarding the contact. Using the mean-field theory for the Bose-Einstein (BEC) to Bardeen-Cooper-Schriefer (BCS) crossover, we also find that the contact is proportional to the square of the gap. We analyze in detail both a homogenous balanced mixture of fermions and its inhomogenous counterpart in a harmonic trap.

DOI
10.48550/arxiv.1012.0236

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As can be inferred from present experiments in ultracold gases, the scattering length is a quantity that determines the thermodynamic state of the gas. As such, there exists a conjugate thermodynamic to it. Here, we show that the recently introduced "contact" is the conjugate of the inverse of the scattering length. We find that this identification allows for a derivation of essentially all the known results regarding the contact. Using the mean-field theory for the Bose-Einstein (BEC) to Bardeen-Cooper-Schriefer (BCS) crossover, we also find that the contact is proportional to the square of the gap. We analyze in detail both a homogenous balanced mixture of fermions and its inhomogenous counterpart in a harmonic trap.
As can be inferred from present experiments in ultracold gases, the scattering length is a quantity that determines the thermodynamic state of the gas. As such, a conjugate thermodynamic variable to it exists. Here, we show that the recently introduced contact is the conjugate of the inverse of the scattering length. We find that this identification, in addition to well-known approximations, allows for a derivation of three of the most relevant results concerning the contact, namely its relation to the adiabatic change of the energy, the general form of the energy and the generalized virial theorem. We find that the current identification of the contact variable depends on the use of the contact approximation for the intermolecular potential but it is independent of whether the gas is made out of fermions or bosons and of the strength of the interaction.
The BCS-BEC (Bose-Einstein condensation) crossover in a lattice is a powerful paradigm that describes how a superconductor deviates from the Bardeen-Cooper-Schrieffer physics as the attractive interaction increases. Optical lattices loaded with binary mixtures of cold atoms allow one to access this phenomenon experimentally in a clean and controlled way. We show that, however, the possibility to study this phenomenon in actual cold-atoms experiments is limited by the effect of the trapping potential. Real-space dynamical mean-field theory calculations show indeed that interactions and the confining potential conspire to pack the fermions in the center of the trap, which approaches a band insulator when the attraction becomes sizeable. Interestingly, the energy gap is spatially more homogeneous than the superfluid condensate order parameter. We show how this physics reflects in several observables, and we propose an alternative strategy to disentangle the effect of the harmonic potential and measure the intrinsic properties resulting from the interaction strength.
PACS. 03.75.Hh – Static properties of condensates; thermodynamical, statistical and structural properties. PACS. 03.75.Ss – Degenerate Fermi gases. PACS. 05.30.Fk – Fermion systems and electron gas. Abstract. – We present a theory for a superfluid Fermi gas near the BCS-BEC crossover, including pairing fluctuation contributions to the free energy similar to that considered by Nozières and Schmitt-Rink for the normal phase. In the strong coupling limit, our theory is able to recover the Bogoliubov theory of a weakly interacting Bose gas with a molecular scattering length very close to the known exact result. We compare our results with recent Quantum Monte Carlo simulations both for the ground state and at finite temperature. Excellent agreement is found for all interaction strengths where simulation results are available. The recent experimental realization of strongly interacting Fermi gases of 6 Li and 40 K atoms near a Feshbach resonance has opened up the exciting possibility of investigating the crossover from a Bardeen-Cooper-Schrieffer (BCS) superfluid to a Bose-Einstein condensate (BEC) [1–5]. In these systems, the inter-atomic interaction strength can be varied by tuning
We elucidate the role of the effective range in the Bose-Einstein-condensate (BEC) to Bardeen-Cooper-Schrieffer (BCS) crossover regime of two-component fermions in three dimensions. In contrast to ultracold Fermi gases near the broad Feshbach resonance, where the interaction can be characterized by the contact-type interaction, the interaction range in general becomes important in the density-induced BEC-BCS crossover discussed in the context of condensed-matter and nuclear systems. By characterizing the nonlocal interaction in terms of the low-energy constants such as scattering length aaa and effective range rrr, we show how the crossover phenomena are affected by nonzero effective ranges. In particular, we show that the superfluid order parameter is strongly suppressed in the high-density regime and the sound velocity exhibits a nonmonotonic behavior reflecting the mechanical stability of the system. Moreover, we point out that the high-momentum tail associated with the contact parameter can be visible when the magnitude of momentum kkk is much less than 1/r1/r1/r. We also discuss the relation between the high-momentum tail and the nuclear contact formalism.
We present a theory of a two-component atomic Fermi gas with tunable attractive contact interactions on a spherical shell going through the Bardeen-Cooper-Schrieffer (BCS)--Bose-Einstein condensation (BEC) crossover, inspired by the realizations of spherical bubble traps for ultracold atoms in microgravity. The derivation follows the BCS-Leggett theory to obtain the gap and number equations. The BCS-BEC crossover can be induced by tuning the interaction, and the properly normalized gap and chemical potential exhibit universal behavior regardless of the planar or spherical geometry. Nevertheless, the spherical-shell geometry introduces another way of inducing the crossover by the curvature. The curvature-induced BCS-BEC crossover is made possible by fixing the particle number and interaction strength while shrinking the sphere, causing a reduction to the ratio of the pairing and kinetic energies and pushing the system toward the BCS limit. The saturation of the superfluid density further confirms that the ground state is a Fermi superfluid.
We investigate the crossover from BCS pairing to molecular Bose-Einstein condensation (BEC) in an atomic gas with two fermion species with masses ${m}_{\ensuremath{\uparrow}}\ensuremath{\ne}{m}_{\ensuremath{\downarrow}}$ tuned through a Feshbach resonance. We present results for the T=0T=0T=0 equation of state as a function of the scattering length including the effects of Gaussian fluctuations about the mean field ground state. We compute the ground state energy as a function of ${m}_{\ensuremath{\uparrow}}/{m}_{\ensuremath{\downarrow}}$ at unitarity and find excellent agreement with the quantum Monte Carlo result for ${m}_{\ensuremath{\uparrow}}/{m}_{\ensuremath{\downarrow}}=6.67$ for a 40K^{40}\mathrm{K}40K-6Li^{6}\mathrm{Li}6Li mixture. We show that the dimer scattering length in the BEC limit as a function of ${m}_{\ensuremath{\uparrow}}/{m}_{\ensuremath{\downarrow}}$ compares well with the exact four-body results of Petrov et al. [J. Phys. B 38, S645 (2005)]. We also derive the condition for trapping frequencies to obtain an unpolarized gas in a harmonic trap.