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arXiv:1007.3957 · Physical Review Letters

Strong and Weak Thermalization of Infinite Nonintegrable Quantum Systems

Mari Carmen Bañuls, J. I. Cirac, M. B. Hastings

Published Feb 4, 2011• 358 citations
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Abstract

When a nonintegrable system evolves out of equilibrium for a long time, local observables are in general expected to attain stationary expectation values, independent of the details of the initial state. But the thermalization of a closed quantum system is not yet well understood. Here we show that it presents indeed a much richer phenomenology than its classical counterpart. Using a new numerical technique, we identify two distinct regimes, strong and weak, occurring for different initial states. Strong thermalization, intrinsically quantum, happens when instantaneous local expectation values converge to the thermal ones. Weak thermalization, well known in classical systems, shows convergence to thermal values only after time averaging. Remarkably, we find a third group of states showing no thermalization, neither strong nor weak, to the time scales one can reliably simulate.

DOI
10.1103/physrevlett.106.050405

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When a nonintegrable system evolves out of equilibrium for a long time, local observables are in general expected to attain stationary expectation values, independent of the details of the initial state. But the thermalization of a closed quantum system is not yet well understood. Here we show that it presents indeed a much richer phenomenology than its classical counterpart. Using a new numerical technique, we identify two distinct regimes, strong and weak, occurring for different initial states. Strong thermalization, intrinsically quantum, happens when instantaneous local expectation values converge to the thermal ones. Weak thermalization, well known in classical systems, shows convergence to thermal values only after time averaging. Remarkably, we find a third group of states showing no thermalization, neither strong nor weak, to the time scales one can reliably simulate.
We experimentally study the ergodic dynamics of a 1D array of 12 superconducting qubits with a transverse field, and identify the regimes of strong and weak thermalization with different initial states. We observe convergence of the local observable to its thermal expectation value in the strong-thermalizaion regime. For weak thermalization, the dynamics of local observable exhibits an oscillation around the thermal value, which can only be attained by the time average. We also demonstrate that the entanglement entropy and concurrence can characterize the regimes of strong and weak thermalization. Our work provides an essential step toward a generic understanding of thermalization in quantum systems.
We study thermalization slowing down of a quantum many-body spin system upon approach to two distinct integrability limits. Motivated by previous studies of classical systems, we identify two thermalization timescales: one quantum Lyapunov timescale is extracted by quantifying operator growth in time on an appropriately defined basis, while another ergodization timescale is related to the statistics of fluctuations of the time-evolved operator around its mean value based on the eigenstate thermalization hypothesis. Using a paradigmatic quantum Ising chain, we find that both timescales diverge upon approach to integrability. We investigate the relative strength of the divergence in the two limits and find that, despite significant qualitative differences in the mechanism of integrability breaking, the timescales diverge in a similar fashion. This allows us to establish a universality of integrability breaking in quantum spin dynamics.
Deriving conditions under which a macroscopic system thermalizes directly from the underlying quantum many-body dynamics of its microscopic constituents is a long-standing challenge in theoretical physics. The well-known eigenstate thermalization hypothesis (ETH) is presumed to be a key mechanism, but has defied rigorous verification for generic systems thus far. A weaker variant (weak ETH), by contrast, is provably true for a large variety of systems, including even many integrable models, but its implications with respect to the problem of thermalization are still largely unexplored. Here we analytically demonstrate that systems satisfying the weak ETH exhibit thermalization for two very natural classes of far-from-equilibrium initial conditions: the overwhelming majority of all pure states with a preset nonequilibrium expectation value of some given local observable, and the Gibbs states of a Hamiltonian which subsequently is subject to a quantum quench in the form of a sudden change of some local system properties.
We explore the role of the initial state on the onset of thermalization in isolated quantum many-body systems after a quench. The initial state is an eigenstate of an initial Hamiltonian ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{I}$ and it evolves according to a different final Hamiltonian ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$. If the initial state has a chaotic structure with respect to ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$, i.e., if it fills the energy shell ergodically, thermalization is certain to occur. This happens when ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{I}$ is a full random matrix, because its states projected onto ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$ are fully delocalized. The results for the observables then agree with those obtained with thermal states at infinite temperature. However, finite real systems with few-body interactions, as the ones considered here, are deprived of fully extended eigenstates, even when described by a nonintegrable Hamiltonian. We examine how the initial state delocalizes as it gets closer to the middle of the spectrum of ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$, causing the observables to approach thermal averages, be the models integrable or chaotic. Our numerical studies are based on initial states with energies that cover the entire lower half of the spectrum of one-dimensional Heisenberg spin-1/2 systems.
Thermalization is the process through which a physical system evolves toward a state of thermal equilibrium. Determining whether or not a physical system will thermalize from an initial state has been a key question in condensed matter physics. Closely related questions are determining whether observables in these systems relax to stationary values, and what those values are. Using tools from computational complexity theory, we demonstrate that given a Hamiltonian on a finite-sized system, determining whether or not it thermalizes or relaxes to a given stationary value is computationally intractable, even for a quantum computer. In particular, we show that the problem of determining whether an observable of a finite-sized quantum system relaxes to a given value is PSPACE-complete, and so no efficient algorithm for determining the value is expected to exist. Further, we show the existence of Hamiltonians for which the problem of determining whether the system thermalizes to the Gibbs expectation value is PSPACE-complete. We also show that the related problem of determining whether the system thermalizes to the microcanonical expectation value is contained in PSPACE and is PSPACE-hard under quantum polynomial time reductions. In light of recent results demonstrating undecidability of thermalization in the thermodynamic limit, our work shows that the intractability of the problem is due to inherent difficulties in many-body physics rather than particularities of infinite systems.
Understanding how closed quantum systems dynamically approach thermal equilibrium presents a major unresolved problem in statistical physics. Generically, non-integrable quantum systems are expected to thermalize as they comply with the Eigenstate Thermalization Hypothesis. However, in the presence of strong disorder, the dynamics can possibly slow down to a degree that systems fail to thermalize on experimentally accessible timescales, as in spin glasses or many-body localized systems. In general, particularly in long-range interacting quantum systems, the specific nature of the disorder necessary for the emergence of a prethermal, metastable state--distinctly separating the timescales of initial relaxation and subsequent slow thermalization--remains an open question. We study an ensemble of Heisenberg spins with a tunable distribution of random coupling strengths realized by a Rydberg quantum simulator. We observe a drastic change in the late-time magnetization when increasing disorder strength. The data is well described by models based on pairs of strongly interacting spins, which are treated as thermal for weak disorder and isolated for strong disorder. Our results indicate a crossover into a pair-localized prethermal regime in a closed quantum system of thousands of spins in the critical case where the exponent of the power law interaction matches the spatial dimension.