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arXiv:1004.0527

Time-dependent attractive thermal quantum force upon a Brownian free particle in the large friction regime

A. O. Bolivar

Published Apr 4, 2010• 0 citations
arXivHTMLPDF

Abstract

We quantize the Brownian motion undergone by a free particle in the absence of inertial force (the so-called large friction regime) as described by the diffusion equation early found out by Einstein in 1905. Accordingly, we are able to come up with a time-dependent attractive quantum force F(t) that acts upon the Brownian free particle as a result of quantum-mechanical thermal fluctuations of a heat bath consisting of a set of quantum harmonic oscillators having the same oscillation frequency /omega in thermodynamic equilibrium at temperature T. More specifically, at zero temperature we predict that the zero-point force is given by F^((T=0)) (t)=-[ω/(1+2\omegat)^(3/2)] \sqrt(γ/2), where γis the friction constant with dimensions of mass per time and /eta the Planck constant divided by 2π. For evolution times t~1/ω, ω~0^14 Hz, /gamma~10^(-10) kg/s, and /eta~10^(-34) m^2 kg/s, we find out F^((T=0)) ~10^(-8) N, which exhibits the same magnitude order as the Casimir electromagnetic quantum force, for instance. Thus, we reckon that novel quantum effects arising from our concept of time-dependent thermal quantum force F(t) may be borne out by some experimental set-up in nanotechnology.

DOI
10.48550/arxiv.1004.0527

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We quantize the Brownian motion undergone by a free particle in the absence of inertial force (the so-called large friction regime) as described by the diffusion equation early found out by Einstein in 1905. Accordingly, we are able to come up with a time-dependent attractive quantum force F(t) that acts upon the Brownian free particle as a result of quantum-mechanical thermal fluctuations of a heat bath consisting of a set of quantum harmonic oscillators having the same oscillation frequency /omega in thermodynamic equilibrium at temperature T. More specifically, at zero temperature we predict that the zero-point force is given by F^((T=0)) (t)=-[ω/(1+2\omegat)^(3/2)] \sqrt(γ/2), where γis the friction constant with dimensions of mass per time and /eta the Planck constant divided by 2π. For evolution times t1/ω, ω0^14 Hz, /gamma10^(-10) kg/s, and /eta10^(-34) m^2 kg/s, we find out F^((T=0)) ~10^(-8) N, which exhibits the same magnitude order as the Casimir electromagnetic quantum force, for instance. Thus, we reckon that novel quantum effects arising from our concept of time-dependent thermal quantum force F(t) may be borne out by some experimental set-up in nanotechnology.
The Brownian motion of a light quantum particle in a heavy classical gas is theoretically described and a new expression for the friction coefficient is obtained for arbitrary temperature. At zero temperature it equals the de Broglie momentum of the mean free path divided by the mean free path. Alternatively, the corresponding mobility of the quantum particle in the classical gas is equal to the square of the mean free path divided by the Planck constant. The Brownian motion of a quantum particle in a quantum environment is also discussed.
In the frames of classical mechanics the generalized Langevin equation is derived for an arbitrary mechanical subsystem coupled to the harmonic bath of a solid. A time-acting temperature operator is introduced for the quantum Klein-Kramers and Smoluchowski equations, accounting for the effect of the quantum thermal bath oscillators. The model of Brownian emitters is theoretically studied and the relevant evolutionary equations for the probability density are derived. The Schrodinger equation is explained via collisions of the target point particles with the quantum force carriers, transmitting the fundamental interactions between the point particles. Thus, electrons and other point particles are no waves and the wavy chapter of quantum mechanics originated for the force carriers. A stochastic Lorentz-Langevin equation is proposed to describe the underlaying Brownian-like motion of the point particles in quantum mechanics. Considering the Brownian dynamics in the frames of the Bohmian mechanics, the density functional Bohm-Langevin equation is proposed, and the relevant Smoluchowski-Bohm equation is derived. A nonlinear master equation is proposed by proper quantization of the classical Klein-Kramers equation. Its equilibrium solution in the exact canonical Gibbs density operator, while the well-known Caldeira-Leggett equation is simply a linearization at high temperature. In the case of a free quantum Brownian particles, a new law for the spreading of the wave packet it discovered, which represents the quantum generalization of the classical Einstein law of Brownian motion. A new projector operator is proposed for the collapse of the wave function of a quantum particle moving in a classical environment. Its application results in dissipative Schrodinger equations, as well as in a new form of dissipative Liouville equation in classical mechanics.
Nonlinear friction forces are a problem in classical Brownian motion for a long time [1]. They are described either by Langevin or by Fokker-Planck equations [2-4]. However, the rigorous generalized Langevin equation is linear, which points out that nonlinear friction forces possess a macroscopic hydrodynamic origin [1]. For this reason, they are not present in the modern quantum theory of open systems [5]. The scope of the present paper is to investigate the nonlinear friction effect on quantum mechanics. The analysis is based on a dissipative Madelung quantum hydrodynamics. Thus, the nonlinear friction is a result of nonlinear non-equilibrium thermodynamics in contrast to the traditional mechanical nonlinear friction forces. A quantum particle in vacuum is described by the Schrodinger equation
A fascinating effect belonging to the field of vacuum forces and fluctuations is that of quantum friction. It refers to the prediction of a dissipative force acting on a moving object due to the quantum vacuum field. In this work, we investigate rotational quantum friction where a diatomic polar molecule rotates around its own center of mass in free space. We quantize the rotational motion and investigate the resulting dissipation due to spontaneous decay. We find in the Markovian regime that a friction torque ∝Ω3\propto Ω^3∝Ω3 persists even for zero temperature, and in agreement with the classical result in the limit of large rotational quantum number lll. Within the non-Markovian short-time regime we find a friction ∝Ω\proptoΩ∝Ω.
Based on the dynamical quantization method we derive a quantum phase-space non-Markovian Smoluchowski equation describing the non-inertial Brownian motion of a harmonic oscillator immersed in a generic environment. In the long-time regime we investigate the tunneling phenomenon by evaluating the quantum Kramers escape rate of a Brownian particle over a potential barrier. As far as a quantum thermal reservoir is concerned, it is found that our steady quantum Kramers rate may depend upon no friction constant in the strong friction domain. This preposterous feature may suggest the existence of non-dissipative quantum tunneling at the low-temperature range, including the zero temperature case. Lastly, we predict that our quantum escape rate non-exponentially decays on the edge of the breakdown of the dissipation-fluctuation relation.