We investigate the condensate density and the condensate fraction of conduction electrons in weak-coupling superconductors by using the BCS theory and the concept of off-diagonal-long-range-order. We discuss the analytical formula of the zero-temperature condensate density of Cooper pairs as a function of Debye frequency and energy gap, and calculate the condensate fraction for some metals. We study the density of Cooper pairs also at finite temperature showing its connection with the gap order parameter and the effects of the electron-phonon coupling. Finally, we analyze similarities and differences between superconductors and ultracold Fermi atoms in the determination of their condensate density by using the BCS theory.
We investigate the condensate density and the condensate fraction of conduction electrons in weak-coupling superconductors by using the BCS theory and the concept of off-diagonal-long-range-order. We discuss the analytical formula of the zero-temperature condensate density of Cooper pairs as a function of Debye frequency and energy gap, and calculate the condensate fraction for some metals. We study the density of Cooper pairs also at finite temperature showing its connection with the gap order parameter and the effects of the electron-phonon coupling. Finally, we analyze similarities and differences between superconductors and ultracold Fermi atoms in the determination of their condensate density by using the BCS theory.
Unification of the BCS and the Bose-Einstein condensation (BEC) theories is surveyed in detail via a generalized BEC (GBEC) finite-temperature statistical formalism. Its major difference with BCS theory is that it can be diagonalized exactly. Under specified conditions it yields the precise BCS gap equation for all temperatures as well as the precise BCS zero-temperature condensation energy for all couplings, thereby suggesting that a BCS condensate is a BE condensate in a ternary mixture of kinematically independent unpaired electrons coexisting with equally proportioned weakly-bound two-electron and two-hole Cooper pairs. Without abandoning the electron-phonon mechanism in moderately weak coupling it suffices, in principle, to reproduce the unusually high values of Tc (in units of the Fermi temperature TF) of 0.01-0.05 empirically reported in the so-called "exotic" superconductors of the Uemura plot, including cuprates, in contrast to the low values of Tc/TF ≤ 10-3 roughly reproduced by BCS theory for conventional (mostly elemental) superconductors. Replacing the characteristic phonon-exchange Debye temperature by a characteristic magnon-exchange one more than twice in size can lead to a simple interaction model associated with spin-fluctuation-mediated pairing.
We investigate the Bose-Einstein condensation of fermionic pairs in a uniform two-component Fermi gas, obtaining an explicit formula for the condensate density as a function of the chemical potential and the energy gap. We analyze the condensate fraction in the crossover from the Bardeen-Cooper-Schrieffer (BCS) state of weakly interacting Cooper pairs to the Bose-Einstein condensate of molecular dimers. By using the local-density approximation we study confined Fermi vapors of alkali-metal atoms for which there is experimental evidence of condensation also on the BCS side of the Feshbach resonance. Our theoretical results are in agreement with these experimental data and give the behavior of the condensate on both sides of the Feshbach resonance at zero temperature.
Using the Boson-Fermion formalism of superconductivity we calculate the condensation energy for several superconductors ranging from conventional to unconventional, or high temperature superconductors. It is calculated as the difference between the Helmholtz free energies of the superconducting and the normal state, which is a gas of N attractive electron gas, while the superconducting state is formed by the condensed Cooper pairs taken as composite bosons, coming from a fraction of the electrons inside the Debye shell, plus those electrons inside and outside the Debye shell that are unable to pair. After giving the analytic expressions for the internal energy U and the entropy S we obtain the Helmholtz free energy F = U -TS for both the superconducting and the normal states as functions of temperature. In the search for universalities, we calculate the ratio of the condensation energy at T=0 to the Sommerfeld constant (the normal state electronic specific heat over the temperature when T it's almost zero) using two different methods: the Boson-Fermion formalism developed here, as well as an analytical expression deduced from a combination of the BCS and Ginzburg-Landau theories. We find for the Boson-Fermion formalism Econd/γ0=0.252Tc1.997, which is the same behavior described by the experimental fit of Kim et al Econd/γ0=0.2Tc2.06 and by the one recently reported by Tallon et al for overdoped cuprate superconductors; while for the Ginzburg-Landau-BCS we get the expression Econd/γ0=0.236Tc2, also in very good agreement with the partifirst method.
We investigate a two-component Fermi gas with unequal spin populations along the BCS-BEC crossover. By using the extended BCS equations and the concept of off-diagonal-long-range-order we derive a formula for the condensate number of Cooper pairs as a function of energy gap, average chemical potential, imbalance chemical potential and temperature. Then we study the zero-temperature condensate fraction of Cooper pairs by varying interaction strength and polarization, finding a depletion of the condensate fraction by increasing the population imbalance. We also consider explicitly the presence of an external harmonic confinement and we study, within the local-density approximation, the phase separation between superfluid and normal phase regions of the polarized fermionic cloud. In particular, we calculate both condensate density profiles and total density profiles from the inner superfluid core to the normal region passing for the interface, where a finite jump in the density is a clear manifestation of this phase-separated regime. Finally, we compare our theoretical results with the available experimental data on the condensate fraction of polarized 6Li atoms [Science 311, 492 (2006)]. These experimental data are in reasonable agreement with our predictions in a suitable range of polarizations, but only in the BCS side of the crossover up to unitarity.
The superfluid density is a fundamental quantity describing the response to a rotation as well as in two-fluid collisional hydrodynamics. We present extensive calculations of the superfluid density ${\ensuremath{\rho}}_{s}$ in the BCS-BEC crossover regime of a uniform superfluid Fermi gas at finite temperatures. We include strong-coupling or fluctuation effects on these quantities within a Gaussian approximation. We also incorporate the same fluctuation effects into the BCS single-particle excitations described by the superfluid order parameter $\ensuremath{\Delta}$ and Fermi chemical potential $\ensuremath{\mu}$, using the Nozi\`eres--Schmitt-Rink approximation. This treatment is shown to be necessary for consistent treatment of ${\ensuremath{\rho}}_{s}$ over the entire BCS-BEC crossover. We also calculate the condensate fraction Nc as a function of the temperature, a quantity which is quite different from the superfluid density ${\ensuremath{\rho}}_{s}$. We show that the mean-field expression for the condensate fraction Nc is a good approximation even in the strong-coupling BEC regime. Our numerical results show how ${\ensuremath{\rho}}_{s}$ and Nc depend on temperature, from the weak-coupling BCS region to the BEC region of tightly bound Cooper pair molecules. In a companion paper [Phys. Rev. A 74, 063626 (2006)], we derive an equivalent expression for ${\ensuremath{\rho}}_{s}$ from the thermodynamic potential, which exhibits the role of the pairing fluctuations in a more explicit manner.
Abstract In weakly coupled BCS superconductors, only electrons within a tiny energy window around the Fermi energy, EF, form Cooper pairs. This may not be the case in strong coupling superconductors such as cuprates, FeSe, SrTiO3 or cold atom condensates where the pairing scale, EB, becomes comparable or even larger than EF. In cuprates, for example, a plausible candidate for the pseudogap state at low doping is a fluctuating pair density wave, but no microscopic model has yet been found which supports such a state. In this work, we write an analytically solvable model to examine pairing phases in the strongly coupled regime and in the presence of anisotropic interactions. Already for moderate coupling we find an unusual finite temperature phase, below an instability temperature Ti, where local pair correlations have non-zero center-of-mass momentum but lack long-range order. At low temperature, this fluctuating pair density wave can condense either to a uniform d-wave super- conductor or the widely postulated pair-density wave phase depending on the interaction strength. Our minimal model offers a unified microscopic framework to understand the emergence of both fluctuating and long range pair density waves in realistic systems.