The Landau–Zener formula provides the probability of non-adiabatic transitions occurring when two energy levels are swept through an avoided crossing. The formula is derived here in a simple calculation that emphasizes the physics responsible for non-adiabatic population transfer.
The approach by Ettore Majorana for non-adiabatic transitions between two quasi-crossing levels is revisited and significantly extended. We rederive the transition probability, known as the Landau-Zener-Stückelberg-Majorana formula, and introduce Majorana's approach to modern readers. This result, typically referred as the Landau-Zener formula, was published by Majorana before Landau, Zener and Stückelberg. Moreover, we go well beyond previous results and we now obtain the full wave function, including its phase, which is important nowadays for quantum control and quantum information. The asymptotic wave function correctly describes the dynamics away from the avoided-level crossing, while it has limited accuracy in that region.
Abstract The Landau–Zener formula describes the diabatic transition probability of a two-level system under linear driving. Its rigorous derivation typically relies on sophisticated mathematical tools, such as special functions, Laplace transforms, or contour integrals. In this work, we present a derivation of the Landau–Zener transition probability using a fundamentally different approach via functional equations. By leveraging integrability, we prove that this transition probability satisfies a functional equation, whose solutions establish the exponential form of the formula. The coefficient in the exponent is then determined through a lowest-order perturbation calculation. This derivation is rigorous and does not involve any sophisticated mathematics. Our work provides insights into the origin of the exponential form of the Landau–Zener transition probability, and shows that the Landau–Zener formula can be viewed as a consequence of integrability, though the two-level Landau–Zener Hamiltonian itself does not satisfy the integrability conditions.
This paper presents analytic formulas for various transition times in the Landau-Zener model. Considerable differences are found between the transition times in the diabatic and adiabatic bases, and between the jump time (the time for which the transition probability rises to the region of its asymptotic value) and the relaxation time (the characteristic damping time of the oscillations which appear in the transition probability after the crossing). These transition times have been calculated by using the exact values of the transition probabilities and their derivatives at the crossing point and approximations to the time evolutions of the transition probabilities in the diabatic basis, derived earlier [N. V. Vitanov and B. M. Garraway, Phys. Rev. A 53, 4288 (1996)], and similar results in the adiabatic basis, derived in the present paper.
We compute Landau-Zener probabilities for three-level systems with a linear sweep of the uncoupled energy levels of the $3\ifmmode\times\else\texttimes\fi{}3$ Hamiltonian matrix H(t). Two symmetry classes of Hamiltonians are studied: For $H(t)\ensuremath{\in}$ su(2) (expressible as a linear combination of the three spin-1 matrices), an analytic solution to the dynamical problem is obtained in terms of the parabolic cylinder D functions. For $H(t)\ensuremath{\in}$ su(3) (expressible as a linear combination of the eight Gell-Mann matrices), numerical solutions are calculated. In the adiabatic regime, full population transfer is obtained asymptotically at large times, but at intermediate times, all three levels are populated, and St\"uckelberg oscillations can manifest from the occurrence of two avoided crossings. For the open system, (wherein interaction with a reservoir occurs), we numerically solve a Markovian quantum master equation for the density matrix with Lindblad operators that models interaction with isotropic white Gaussian noise. We find that St\"uckelberg oscillations are suppressed and that the decoherence cannot be modeled in terms of a simple exponential.