It is argued that a typical many-body energy eigenstate has a well-defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems with eigenstate energies equivalent to finite temperatures. When quasi-static evolution of a system is adiabatic (in the quantum mechanical sense), two coupled subsystems can transfer heat from one subsystem to another and yet remain in an energy eigenstate. To explicitly construct the entropy from the wave function, degrees of freedom are divided into two unequal parts. It is argued that the entanglement entropy between these two subsystems is the thermodynamic entropy per degree of freedom for the smaller subsystem. This is done by tracing over the larger subsystem to obtain a density matrix and calculating the diagonal and off-diagonal contributions to the entanglement entropy.
It is argued that a typical many-body energy eigenstate has a well-defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems with eigenstate energies equivalent to finite temperatures. When quasi-static evolution of a system is adiabatic (in the quantum mechanical sense), two coupled subsystems can transfer heat from one subsystem to another and yet remain in an energy eigenstate. To explicitly construct the entropy from the wave function, degrees of freedom are divided into two unequal parts. It is argued that the entanglement entropy between these two subsystems is the thermodynamic entropy per degree of freedom for the smaller subsystem. This is done by tracing over the larger subsystem to obtain a density matrix and calculating the diagonal and off-diagonal contributions to the entanglement entropy.
We consider a chaotic many-body system (i.e., one that satisfies the eigenstate thermalization hypothesis) that is split into two subsystems, with an interaction along their mutual boundary, and study the entanglement properties of an energy eigenstate with nonzero energy density. When the two subsystems have nearly equal volumes, we find a universal correction to the entanglement entropy that is proportional to the square root of the system's heat capacity (or a sum of capacities, if there are conserved quantities in addition to energy). This phenomenon was first noted by Vidmar and Rigol in a specific system; our analysis shows that it is generic, and expresses it in terms of thermodynamic properties of the system. Our conclusions are based on a refined version of a model of a chaotic eigenstate originally due to Deutsch, and analyzed more recently by Lu and Grover.
Using arguments built on ergodicity, we derive an analytical expression for the Renyi entanglement entropies which, we conjecture, applies to the finite-energy density eigenstates of chaotic many-body Hamiltonians. The expression is a universal function of the density of states and is valid even when the subsystem is a finite fraction of the total system-a regime in which the reduced density matrix is not thermal. We find that in the thermodynamic limit, only the von Neumann entropy density is independent of the subsystem to the total system ratio V_{A}/V, while the Renyi entropy densities depend nonlinearly on V_{A}/V. Surprisingly, Renyi entropies S_{n} for n>1 are convex functions of the subsystem size, with a volume law coefficient that depends on V_{A}/V, and exceeds that of a thermal mixed state at the same energy density. We provide two different arguments to support our results: the first one relies on a many-body version of Berry's formula for chaotic quantum-mechanical systems, and is closely related to the eigenstate thermalization hypothesis. The second argument relies on the assumption that for a fixed energy in a subsystem, all states in its complement allowed by the energy conservation are equally likely. We perform an exact diagonalization study on quantum spin-chain Hamiltonians to test our analytical predictions.
We study the properties of mixed states obtained from eigenstates of many-body lattice Hamiltonians after tracing out part of the lattice. Two scenarios emerge for generic systems: (i) The diagonal entropy becomes equivalent to the thermodynamic entropy when a few sites are traced out (weak typicality); and (ii) the von Neumann (entanglement) entropy becomes equivalent to the thermodynamic entropy when a large fraction of the lattice is traced out (strong typicality). Remarkably, the results for few-body observables obtained with the reduced, diagonal, and canonical density matrices are very similar to each other, no matter which fraction of the lattice is traced out. Hence, for all physical quantities studied here, the results in the diagonal ensemble match the thermal predictions.
Whether or not the thermodynamic entropy is equal to the entanglement entropy of an eigenstate is of fundamental interest, and is closely related to the eigenstate thermalization hypothesis (ETH). However, this has never been exploited as a diagnostic tool in many-body- localized (MBL) systems. In this work, we perform this diagnostic test on a clean interacting system (subjected to a static electric field) that exhibits three distinct phases: integrable, non-integrable ergodic and non-integrable MBL. We find that in the non-integrable phase, the equivalence between the thermodynamic entropy and the entanglement entropy of individual eigenstates holds. In sharp contrast, in the integrable and non-integrable MBL phases, the entanglement entropy shows large eigenstate-to-eigenstate fluctuations, and differs from the thermodynamic entropy. Thus the non-integrable MBL phase violates ETH similar to an integrable system; however, a key difference is that the magnitude of the entanglement entropy in the MBL phase is significantly smaller than in the integrable phase, where the entanglement entropy is of the same order of magnitude as in the non-integrable phase, but with a lot of eigenstate-to-eigenstate fluctuations. Quench dynamics from an initial CDW state independently supports the validity of the ETH in the ergodic phase and its violation in the MBL phase.
A system composed of identical spins and described by a quantum mechanical pure state is analyzed within the statistical framework presented in Part I of this work. We explicitly derive the typical values of the entropy, of the energy, and of the equilibrium reduced density matrix of a subsystem for the two different statistics introduced in Part I. In order to analyze their consistency with thermodynamics, these quantities of interest are evaluated in the limit of large number of components of the isolated system. The main results can be summarized as follows: typical values of the entropy and of the equilibrium reduced density matrix as functions of the internal energy in the fixed expectation energy ensemble do not satisfy the requirement of thermodynamics. On the contrary, the thermodynamical description is recovered from the random pure state ensemble (RPSE), provided that one considers systems large enough. The thermodynamic limit of the considered properties for the spin system reveals a number of important features. First canonical statistics (and thus, canonical typicality as long as the fluctuations around the average value are small) emerges without the need of assuming the microcanonical space for the global pure state. Moreover, we rigorously prove (i) the equivalence of the "global temperature," derived from the entropy equation of state, with the "local temperature" determining the canonical state of the subsystems; and (ii) the equivalence between the RPSE typical entropy and the canonical entropy for the overall system.
One key issue of the foundation of statistical mechanics is the emergence of equilibrium ensembles in isolated and closed quantum systems. Recently, it was predicted that in the thermodynamic (N→∞) limit of large quantum many-body systems, canonical density matrices emerge for small subsystems from almost all pure states. This notion of canonical typicality is assumed to originate from the entanglement between subsystem and environment and the resulting intrinsic quantum complexity of the many-body state. For individual eigenstates, it has been shown that local observables show thermal properties provided the eigenstate thermalization hypothesis holds, which requires the system to be quantum-chaotic. In the present paper, we study the emergence of thermal states in the regime of a quantum analog of a mixed phase space. Specifically, we study the emergence of the canonical density matrix of an impurity upon reduction from isolated energy eigenstates of a large but finite quantum system the impurity is embedded in. Our system can be tuned by means of a single parameter from quantum integrability to quantum chaos and corresponds in between to a system with mixed quantum phase space. We show that the probability for finding a canonical density matrix when reducing the ensemble of energy eigenstates of the finite many-body system can be quantitatively controlled and tuned by the degree of quantum chaos present. For the transition from quantum integrability to quantum chaos, we find a continuous and universal (i.e., size-independent) relation between the fraction of canonical eigenstates and the degree of chaoticity as measured by the Brody parameter or the Shannon entropy.