Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:0905.2873 · New Journal of Physics

Quantum dynamics of resonant molecule formation in waveguides

V S Melezhik, P Schmelcher

Published Jul 15, 2009• 41 citations
arXivHTMLPDF

Abstract

We explore the quantum dynamics of heteronuclear atomic collisions in waveguides and demonstrate the existence of a novel mechanism for the resonant formation of polar molecules. The molecular formation probabilities can be tuned by changing the trap frequencies that characterize the transverse modes of the atomic species. The origin of this effect is the confinement-induced mixing of the relative and center of mass motions in the atomic collision process leading to a coupling of the diatomic continuum to the center of mass excited molecular states in closed transverse channels.

DOI
10.1088/1367-2630/11/7/073031

Related papers

Resonances in ultracold collisions confined by atomic traps

Vladimir S. Melezhik

We have developed a method for treating ultracold pair collisions in confined geometry of tight atomic waveguides. With this approach we have predicted and analyzed a few novel resonant and multichannel effects induced by confining traps in ultracold atomic collisions. In this report we discuss our model yielding the shifts and widths of magnetic Feshbach resonances in tight atomic waveguides. We also briefly discuss a resonant mechanism of molecule formation in atomic traps with transferring the energy release to the center-of-mass excitation while forming molecule and dipolar confinement-induced resonances in waveguides. These results could potentially be used experimentally.

Journal of Physics Conference Series•Apr 9, 2014•1 citation

Diatomic molecule in the polar trap

Yurij Yaremko, Maria Przybylska, Andrzej J. Maciejewski

Abstract We discuss the trapping of heteronuclear diatomic molecules prepared in their electronic and vibrational ground states. We tune and shape the trapping potential for bosonic polar molecules in superpositions of rotational states by dressing rotational excitations with a static sextupole electric field. The translational motion of a molecule is treated classically. We examine the Hamiltonian which governs the center of mass dynamics. The effective potential has a global minimum that provides the trapping ability of this trap. The first term of its Taylor series expansion, corresponding to the quadratic Stark shifts, results in the integrable potential. In terms of cylindrical coordinates the center of mass Hamiltonian splits into axial and radial parts. Corresponding trajectories are parameterized by elliptic functions. At low electric fields, the non-approximated Hamiltonian is treated as a small perturbation of the mentioned integrable system described by Kolmogorov–Arnold–Moser theory. The applicability of this approximation is discussed and illustrated using the Poincaré cross-section method. We present results of numerical simulations illustrating the trapping and confinement of a polar molecule in the trap.

Journal of Physics B Atomic Molecular and Optical Physics•Feb 10, 2025•1 citation

Coherent Molecule Formation in Anharmonic Potentials Near Confinement-Induced Resonances

Simon Sala, G. Zürn, Thomas Lompe +5 more

We perform a theoretical and experimental study of a system of two ultracold atoms with tunable interaction in an elongated trapping potential. We show that the coupling of center-of-mass and relative motion due to an anharmonicity of the trapping potential leads to a coherent coupling of a state of an unbound atom pair and a molecule with a center of mass excitation. By performing the experiment with exactly two particles we exclude three-body losses and can therefore directly observe coherent molecule formation. We find quantitative agreement between our theory of inelastic confinement-induced resonances and the experimental results. This shows that the effects of center-of-mass to relative-motion coupling can have a significant impact on the physics of quantum systems near center-of-mass to relative-motion coupling resonances.

arXiv:1303.1844•Physical Review Letters•May 16, 2013•65 citations

Multichannel atomic scattering and confinement-induced resonances in waveguides

Shahpoor Saeidian, Vladimir S. Melezhik, Peter Schmelcher

We develop a grid method for multichannel scattering of atoms in a waveguide with harmonic confinement. This approach is employed to extensively analyze the transverse excitations and deexcitations as well as resonant scattering processes. Collisions of identical bosonic and fermionic as well as distinguishable atoms in harmonic traps with a single frequency $\ensuremath{\omega}$ permitting the center-of-mass (c.m.) separation are explored in depth. In the zero-energy limit and single mode regime we reproduce the well-known confinement-induced resonances (CIRs) for bosonic, fermionic, and heteronuclear collisions. In the case of the multimode regime up to four open transverse channels are considered. Previously obtained analytical results are extended significantly here. Series of Feshbach resonances in the transmission behavior are identified and analyzed. The behavior of the transmission with varying energy and scattering lengths is discussed in detail. The dual CIR leading to a complete quantum suppression of atomic scattering is revealed in multichannel scattering processes. Possible applications include, e.g., cold and ultracold atom-atom collisions in atomic waveguides and electron-impurity scattering in quantum wires.

arXiv:0802.3682•Physical Review A•Apr 25, 2008•46 citations

Matter-wave bistability in coupled atom-molecule quantum gases

Lei Jiang, Han Pu, Andrew J. Robertson +1 more

We study the matter-wave bistability in coupled atom-molecule quantum gases, in which heteronuclear molecules are created via an interspecies Feshbach resonance involving either two-species Bose or two-species Fermi atoms at zero temperature. We show that the resonant two-channel Bose model is equivalent to the nondegenerate parametric down-conversion in quantum optics, while the corresponding Fermi model can be mapped to a quantum optics model that describes a single-mode laser field interacting with an ensemble of inhomogeneously broadened two-level atoms. Using these analogies and the fact that both models are subject to the Kerr nonlinearity due to the two-body $s$-wave collisions, we show that under proper conditions, the population in the molecular state in both models can be made to change with the Feshbach detuning in a bistable fashion.

arXiv:0907.4779•Physical Review A•Jan 20, 2010•3 citations

Inelastic Confinement-Induced Resonances in Low-Dimensional Quantum Systems

Simon Sala, Philipp‐Immanuel Schneider, Alejandro Sáenz

A theoretical model is presented describing the confinement-induced resonances observed in the recent loss experiment of Haller et al. [Phys. Rev. Lett. 104, 153203 (2010)]. These resonances originate from possible molecule formation due to the coupling of center-of-mass and relative motion. A corresponding model is verified by ab initio calculations and predicts the resonance positions in 1D as well as in 2D confinement in agreement with the experiment. This resolves the contradiction of the experimental observations to previous theoretical predictions.

arXiv:1104.1561•Physical Review Letters•Aug 16, 2012•60 citations
We explore the quantum dynamics of heteronuclear atomic collisions in waveguides and demonstrate the existence of a novel mechanism for the resonant formation of polar molecules. The molecular formation probabilities can be tuned by changing the trap frequencies that characterize the transverse modes of the atomic species. The origin of this effect is the confinement-induced mixing of the relative and center of mass motions in the atomic collision process leading to a coupling of the diatomic continuum to the center of mass excited molecular states in closed transverse channels.
We have developed a method for treating ultracold pair collisions in confined geometry of tight atomic waveguides. With this approach we have predicted and analyzed a few novel resonant and multichannel effects induced by confining traps in ultracold atomic collisions. In this report we discuss our model yielding the shifts and widths of magnetic Feshbach resonances in tight atomic waveguides. We also briefly discuss a resonant mechanism of molecule formation in atomic traps with transferring the energy release to the center-of-mass excitation while forming molecule and dipolar confinement-induced resonances in waveguides. These results could potentially be used experimentally.
Abstract We discuss the trapping of heteronuclear diatomic molecules prepared in their electronic and vibrational ground states. We tune and shape the trapping potential for bosonic polar molecules in superpositions of rotational states by dressing rotational excitations with a static sextupole electric field. The translational motion of a molecule is treated classically. We examine the Hamiltonian which governs the center of mass dynamics. The effective potential has a global minimum that provides the trapping ability of this trap. The first term of its Taylor series expansion, corresponding to the quadratic Stark shifts, results in the integrable potential. In terms of cylindrical coordinates the center of mass Hamiltonian splits into axial and radial parts. Corresponding trajectories are parameterized by elliptic functions. At low electric fields, the non-approximated Hamiltonian is treated as a small perturbation of the mentioned integrable system described by Kolmogorov–Arnold–Moser theory. The applicability of this approximation is discussed and illustrated using the Poincaré cross-section method. We present results of numerical simulations illustrating the trapping and confinement of a polar molecule in the trap.
We perform a theoretical and experimental study of a system of two ultracold atoms with tunable interaction in an elongated trapping potential. We show that the coupling of center-of-mass and relative motion due to an anharmonicity of the trapping potential leads to a coherent coupling of a state of an unbound atom pair and a molecule with a center of mass excitation. By performing the experiment with exactly two particles we exclude three-body losses and can therefore directly observe coherent molecule formation. We find quantitative agreement between our theory of inelastic confinement-induced resonances and the experimental results. This shows that the effects of center-of-mass to relative-motion coupling can have a significant impact on the physics of quantum systems near center-of-mass to relative-motion coupling resonances.
We develop a grid method for multichannel scattering of atoms in a waveguide with harmonic confinement. This approach is employed to extensively analyze the transverse excitations and deexcitations as well as resonant scattering processes. Collisions of identical bosonic and fermionic as well as distinguishable atoms in harmonic traps with a single frequency $\ensuremath{\omega}$ permitting the center-of-mass (c.m.) separation are explored in depth. In the zero-energy limit and single mode regime we reproduce the well-known confinement-induced resonances (CIRs) for bosonic, fermionic, and heteronuclear collisions. In the case of the multimode regime up to four open transverse channels are considered. Previously obtained analytical results are extended significantly here. Series of Feshbach resonances in the transmission behavior are identified and analyzed. The behavior of the transmission with varying energy and scattering lengths is discussed in detail. The dual CIR leading to a complete quantum suppression of atomic scattering is revealed in multichannel scattering processes. Possible applications include, e.g., cold and ultracold atom-atom collisions in atomic waveguides and electron-impurity scattering in quantum wires.
We study the matter-wave bistability in coupled atom-molecule quantum gases, in which heteronuclear molecules are created via an interspecies Feshbach resonance involving either two-species Bose or two-species Fermi atoms at zero temperature. We show that the resonant two-channel Bose model is equivalent to the nondegenerate parametric down-conversion in quantum optics, while the corresponding Fermi model can be mapped to a quantum optics model that describes a single-mode laser field interacting with an ensemble of inhomogeneously broadened two-level atoms. Using these analogies and the fact that both models are subject to the Kerr nonlinearity due to the two-body sss-wave collisions, we show that under proper conditions, the population in the molecular state in both models can be made to change with the Feshbach detuning in a bistable fashion.
A theoretical model is presented describing the confinement-induced resonances observed in the recent loss experiment of Haller et al. [Phys. Rev. Lett. 104, 153203 (2010)]. These resonances originate from possible molecule formation due to the coupling of center-of-mass and relative motion. A corresponding model is verified by ab initio calculations and predicts the resonance positions in 1D as well as in 2D confinement in agreement with the experiment. This resolves the contradiction of the experimental observations to previous theoretical predictions.