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arXiv:0905.1492 · Physical Review A

Analytic description of atomic interaction at ultracold temperatures: The case of a single channel

Bo Gao

Published Jul 2, 2009• 60 citations
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Abstract

We present analytic descriptions of atomic interaction at ultracold temperatures using both single-channel and multichannel quantum-defect theories. In the case of a single channel, addressed in this paper, the expansion of Gao [Phys. Rev. A 58, 4222 (1998)] is generalized to higher orders for angular momentum $l\ensuremath{\ge}2$ to give a more complete description of ultracold scattering, including an analytic description of ultracold shape resonances of arbitrary $l$. We also introduce a generalized scattering length that is well defined and useful for all partial waves to replace the traditional definition that fails for $l\ensuremath{\ge}2$ due to the long-range van der Waals interaction. The results are used in a companion paper to derive analytic descriptions of atomic interaction around a magnetic Feshbach resonance of arbitrary angular momentum $l$.

DOI
10.1103/physreva.80.012702

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We present analytic descriptions of atomic interaction at ultracold temperatures using both single-channel and multichannel quantum-defect theories. In the case of a single channel, addressed in this paper, the expansion of Gao [Phys. Rev. A 58, 4222 (1998)] is generalized to higher orders for angular momentum l\ensuremath≥2l\ensuremath{\ge}2l\ensuremath≥2 to give a more complete description of ultracold scattering, including an analytic description of ultracold shape resonances of arbitrary lll. We also introduce a generalized scattering length that is well defined and useful for all partial waves to replace the traditional definition that fails for l\ensuremath≥2l\ensuremath{\ge}2l\ensuremath≥2 due to the long-range van der Waals interaction. The results are used in a companion paper to derive analytic descriptions of atomic interaction around a magnetic Feshbach resonance of arbitrary angular momentum lll.
Starting from a multichannel quantum-defect theory, we derive analytic descriptions of a magnetic Feshbach resonance in an arbitrary partial wave lll and the atomic interactions around it. An analytic formula, applicable to both broad and narrow resonances of arbitrary lll, is presented for ultracold atomic scattering around a Feshbach resonance. Other related issues addressed include (a) the parametrization of a magnetic Feshbach resonance of arbitrary lll, (b) rigorous definitions of ``broad'' and ``narrow'' resonances of arbitrary lll and their different scattering characteristics, and (c) the tuning of the effective range and the generalized effective range by a magnetic field.
We develop an analytical model for ultracold atom–ion collisions using the multichannel quantum-defect formalism. The model is based on analytical solutions of the r −4 long-range potential and on the application of a frame transformation between asymptotic and molecular bases. This approach allows the description of atom–ion interaction in the ultracold domain in terms of only three parameters: the singlet and triplet scattering lengths, assumed to be independent of the relative motion angular momentum, and the lead dispersion coefficient of the asymptotic potential. We also introduce corrections to the scattering lengths that improve the accuracy of our quantum-defect model for higher-order partial waves, a particularly important result for an accurate description of shape and Feshbach resonances at finite temperature. The theory is applied to the system composed of a 40 Ca + ion and a Na atom, and compared with numerical coupled-channel calculations carried out using ab initio potentials. For this particular system, we investigate the spectrum of bound states, the rate of charge-transfer processes and the collision rates in the presence of magnetic Feshbach resonances at zero and finite temperature.
We have developed a model of Feshbach resonances in gases of ultracold alkali-metal atoms using the ideas of multichannel quantum-defect theory. Our model requires just three parameters describing the interactions---the singlet and triplet scattering lengths, and the long-range van der Waals coefficient---in addition to known atomic properties. Without using any further details of the interactions, our approach can accurately predict the locations of resonances. It can also be used to find the singlet and triplet scattering lengths from measured resonance data. We apply our technique to 6Li-40K^{6}\text{L}\text{i-}^{40}\text{K}6Li-40K and $^{40}\text{K}\text{\ensuremath{-}}^{87}\text{R}\text{b}$ scattering, obtaining good agreement with experimental results, and with the more computationally intensive coupled channels technique.
Feshbach resonances in ultracold collisions often result from an interplay between many collision channels. Simple two-channel models can be introduced to capture the basic features, but cannot fully reproduce the situation when several resonances from different closed channels contribute to the scattering process. Using the formalism of multichannel quantum defect theory we develop an analytical model of overlapping Feshbach resonances. We find a general formula for the variation of the scattering length with magnetic field in the vicinity of an arbitrary number of resonances, characterized by simple parameters. Our formula is in excellent agreement with numerical coupled-channel calculations for several cases of overlapping resonances in the collisions of two 7{}^{7}7Li atoms or two Cs atoms.
We present a multichannel quantum-defect theory for slow atomic collisions that takes advantages of the analytic solutions for the long-range potential and both the energy and angular momentum insensitivities of the short-range parameters. The theory provides an accurate and complete account of scattering processes, including shape and Feshbach resonances, in terms of a few parameters such as the singlet and triplet scattering lengths. As an example, results for $^{23}\mathrm{Na}\ensuremath{-}^{23}\mathrm{Na}$ scattering are presented and compared to close-coupling calculations.