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arXiv:0905.1012

Weak-Coupling Limit. I A Contraction Semigroup for Infinite Subsystems

David Taj

Published May 7, 2009• 2 citations
arXivHTMLPDF

Abstract

We consider the class of quantum mechanical master equations defined on a generic Banach space, arising by projecting weakly perturbed one-parameter groups of isometries. We show that the possible semigroup approximations are far from unique. However, uniqueness can be reestablished through the introduction of a dynamical time averaging map. The generator of the resulting Contraction Semigroup is always well defined, irrespective of the dimensions of the projected subspace, and of the spectral properties of its free dynamics. We show how our approach includes and generalizes the preexisting literature.

DOI
10.48550/arxiv.0905.1012

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We consider the class of quantum mechanical master equations defined on a generic Banach space, arising by projecting weakly perturbed one-parameter groups of isometries. We show that the possible semigroup approximations are far from unique. However, uniqueness can be reestablished through the introduction of a dynamical time averaging map. The generator of the resulting Contraction Semigroup is always well defined, irrespective of the dimensions of the projected subspace, and of the spectral properties of its free dynamics. We show how our approach includes and generalizes the preexisting literature.
In a recent work we have found a contraction semigroup able to correctly approximate a projected and perturbed one-parameter group of isometries in a generic Banach space, in the limit of weak-coupling. Here we study its generator by specializing to W∗W^*W∗-algebras: after defining a Physical Subsystem in terms of a completely positive projecting conditional expectation, we find that it generates a Quantum Dynamical Semigroup. As a consequence of uniqueness and strong generality (well defined dynamics, irrespective of the Physical Subsystem spectral properties or dimensions), its generator deserves to be referred as "the" Quantum Fokker-Planck Equation. We then provide important examples of the limit dynamics, one of which constitutes a new Quantum generalization of the celebrated Fermi Golden Rule.
We developed the projection method to derive an analog of the quantum master equation for propagators rather than density matrices themselves. As these propagators are superoperators, we call them superoperator master equations. Furthermore, as the projector maps superoperators to superoperators, we call it a hyperprojector. We gave general perturbative expansions for generators of the weak coupling superoperator master equation and the stroboscopic limit superoperator master equation. After that, we considered a particular example of a hyperprojector that is the infinite time average of unitary dynamics. We call it the averaging hyperprojector. We discussed the properties of this hyperprojector and its physical meaning. Then, we illustrated our general second order superoperator master equations arising in the weak coupling limit and the stroboscopic limit, taking the averaging hyperprojector as an example, which we call effective dynamics. We discussed some properties of these superoperator master equations, in particular, the entropy increase.
We study a class of self-adjoint operators defined on the direct sum of two Hilbert spaces: a finite dimensional one called sometimes a “small subsystem” and an infinite dimensional one called a “reservoir.” The operator, which we call a “Friedrichs Hamiltonian,” has a small coupling constant in front of its off-diagonal term. It is well known that under some conditions in the weak coupling limit the appropriately rescaled evolution in the interaction picture converges to a contractive semigroup when restricted to the subsystem. We show that in this model, the properly renormalized and rescaled evolution converges on the whole space to a new unitary evolution, which is a dilation of the above mentioned semigroup. Similar results have been studied before (Accardi et al., 1990) in more complicated models under the name of “stochastic limit.”
We study a class of self-adjoint operators defined on the direct sum of two Hilbert spaces: a finite dimensional one called sometimes a “small subsystem” and an infinite dimensional one – a “reservoir”. The operator, which we call a “Friedrichs Hamiltonian”, has a small coupling constant in front of its off-diagonal term. It is well known that under some conditions in the weak coupling limit the appropriately rescaled evolution in the interaction picture converges to a contractive semigroup when restricted to the subsystem. We show that in this model, the properly renormalized and rescaled evolution converges on the whole space to a new unitary evolution, which is a dilation of the above mentioned semigroup. Similar results have been studied before [AFL] in more complicated models and they are usually referred to as ”stochastic Limit”.
Background: Operator algebras and quantum dynamical semigroups are the mathematical tools of choice for understanding open quantum systems, especially in infinite-dimensional spaces. Such tools are extremely important for the time development of quantum systems out of equilibium under the influence of environment, where conventional finite dimensional methods do not include all possibilities for interaction. Objective: The objects of the present research are the r-properties and the decompositions of generators of quantum dynamical semigroups on infinite-dimensional spaces including their Hamiltonian and dissipative part, semigroup continuity, stationary states, and positivity improvement. The aim is to set a fundament in order to think about long-time dynamics in open quantum systems. Methods: The theorem Hille–Yosida is used to get conditions for the semigroup strongly continuous generated by unbounded operators. The time-evolution operator of the system is approximated with both Gaussian quadrature and Monte Carlo integration during infinitesimal time slices, by using Inf-LCHS in conjunction. Generators were studied under decomposition of their Hamiltonian and dissipative parts, while commutant algebras were investigated for irreducibility and positivity enhancement. Results: Most systems studied for these properties presented a singular decomposition, strong and weak semigroup continuity, existence of stationary states and positivity improvement. The counterexamples were the systems with in a lack of verification for dissipative parts, and they lost smoothing property, uniqueness of decomposition, partial semigroup continuity or large errors in approximation when we perform numerically. Conclusions: The combination of the methods of operator algebra with state-of-the-art simulation techniques yields a powerful approach to study infinite-dimensional quantum dynamics. Although dissipative components are not yet completely characterized, the results improve our understanding of generator structures and long-term system behavior which will help future work in quantum statistical mechanics and quantum information theory.
In recent years, digraph induced generators of quantum dynamical semigroups have been introduced and studied, particularly in the context of unique relaxation and invariance. We define the class of pair block diagonal generators, which allows for additional interaction coefficients but preserves the main structural properties. Namely, when the basis of the underlying Hilbert space is given by the eigenbasis of the Hamiltonian (for example the generic semigroups), then the action of the semigroup leaves invariant the diagonal and off-diagonal matrix spaces. In this case, we explicitly compute all invariant states of the semigroup. In order to define this class we provide a characterization of when the Gorini- Kossakowski-Sudarshan-Lindblad (GKSL) equation defines a proper generator when arbitrary Lindblad operators are allowed (in particular, they do not need to be trace- less as demanded by the GKSL Theorem). Moreover, we consider the converse con- struction to show that every generator naturally gives rise to a digraph, and that under certain assumptions the properties of this digraph can be exploited to gain knowledge of both the number and the structure of the invariant states of the corre- sponding semigroup. We also consider more general constructions on the von Neumann algebra of all bounded linear operators on a Hilbert space, perhaps infinite dimensional. In partic- ular, we prove that for every semigroup of Schwarz maps on such an algebra which has a subinvariant faithful normal state there exists an associated semigroup of con- tractions on the space of Hilbert-Schmidt operators of the Hilbert space. Moreover, we show that if the original semigroup is weak∗ continuous then the associated semigroup is strongly continuous. We introduce the notion of the extended generator of a semigroup on the bounded operators of a Hilbert space with respect to an or- thonormal basis of the Hilbert space. We describe this form of the generator of a quantum Markov semigroup on the von Neumann algebra of all bounded linear op- erators on a Hilbert space which has an invariant faithful normal state under the assumption that the generator of the associated semigroup has compact resolvent, or under the assumption that the minimal unitary dilation of the associated semigroup of contractions is compact.