It is argued that the world is a dissipative dynamic system, a phase flow of which is formed by conformally-symplectic mapping. The key assumption is that the concept of energy in microcosm makes sense only for the steady motions corresponding to quantum eigenstates. The constant, which determines the exponential phase volume contraction, is supposed to be a new universal constant, in addition to the speed of light and Planck constant. It is shown that statistical treatment of quantum objects as the ensembles concentrated on smooth connected attractors provides a simple explanation of stochastic behaviour of these objects as well as leads to a natural interpretation of the wave function, stationary Schrodinger equation, and scattering matrix. To validate the general hypotheses stated in the work, some physical models are presented. In particular, the models support the view that the inertial motion and quantum properties are basically determined by the vacuum as a dynamic subsystem. The matter-vacuum interaction is described formally by means of multivalued Hamilton function. A drawback of all these models is the non-locality of equations of motion stemming from the non-locality of variation of multivalued Hamilton function. This drawback can be overcome in the field theory using multivalued functionals with a local first variation opened by S. P. Novikov. Hence, a prospect of construction of the unified field theory in Einstein spirit, without a procedure of quantization is opened.
It is argued that the world is a dissipative dynamic system, a phase flow of which is formed by conformally-symplectic mapping. The key assumption is that the concept of energy in microcosm makes sense only for the steady motions corresponding to quantum eigenstates. The constant, which determines the exponential phase volume contraction, is supposed to be a new universal constant, in addition to the speed of light and Planck constant. It is shown that statistical treatment of quantum objects as the ensembles concentrated on smooth connected attractors provides a simple explanation of stochastic behaviour of these objects as well as leads to a natural interpretation of the wave function, stationary Schrodinger equation, and scattering matrix. To validate the general hypotheses stated in the work, some physical models are presented. In particular, the models support the view that the inertial motion and quantum properties are basically determined by the vacuum as a dynamic subsystem. The matter-vacuum interaction is described formally by means of multivalued Hamilton function. A drawback of all these models is the non-locality of equations of motion stemming from the non-locality of variation of multivalued Hamilton function. This drawback can be overcome in the field theory using multivalued functionals with a local first variation opened by S. P. Novikov. Hence, a prospect of construction of the unified field theory in Einstein spirit, without a procedure of quantization is opened.
Despite early developments on the foundations of quantum mechanics concern the wave function, quantum statistics has been developed with the density matrix formalism, leading to very important results in explaining molecular observations. Only recently, several authors argued a new interpretation by focusing on the wave function representing the quantum state of an isolated system, showing how a single wave function can exhibit statistical properties and generate the same results expected in the standard quantum statistical framework. Starting from these results, investigation on the foundations of quantum statistical mechanics has gained recently a renewed interest. As a matter of fact, the possibility of studying single molecule properties as well as the need of a better understanding of the effect of quantum dynamics, in order to develop new nanoscaled materials suitable to quantum computing tasks, have opened new intriguing questions leading to quantum statistical approaches far from being well understood and accepted. In this framework the behaviour of a single realization of quantum systems has gained a central role in the description of molecular systems. Furthermore, in recent years, an increasing number of studies has been presented on quantum dynamics through the numerical solution of the Schrödinger equation for systems of interacting components. These studies demonstrates that Quantum Dynamics Simulations could be a practicable route. In order to study phenomena such as dissipation, relaxation and thermalization, the focus has to be moved from isolated molecules to modular systems made of mutual interacting components, with model Hamiltonians possessing a sufficiently low dimensional representation. An important issue concerns the rules to be employed for the choice of the initial quantum state for the simulation of isolated systems. As long as one considers molecular degrees of freedom interacting with a (model) environment, there are no reasons to select a particular quantum state for the overall system and, therefore, a random choice has to be performed amongst a well defined statistical ensemble of pure states. Furthermore, one would like to operate a choice assuring that the simulation of the system is in a well defined thermal state with given temperature. This necessarily calls for a statistical description like for classical systems. A useful parametrization of the wave function will be presented in order to highlight the most appropriate variable for the statistical analysis. In particular some of them, called phases, retain all the dynamical information whereas the others, called populations, are the constants of motion. The latter, in particular are very important because they describe the equilibrium properties strictly related to the thermodynamic description. Since the dynamics of wave function does not supply any information about populations, the definition of a probability distribution on these variables is required. Different probability distributions on populations have been proposed, only on the bases of reasonable assumptions and they validation has been performed only with a posteriori considerations. In particular Fresch and Moro have demonstrated how the agreement with thermodynamics can be employed to discriminate different probability distributions on pure states. This had led the uniform ensembles to be, up to now, the most self-consistent models for quantum pure states. However, in this thesis I will highlight a drawback of the uniform distribution ensemble that can be described as follow: if we bring into contact two systems, even through a perturbative interaction, we are not able to describe the equilibrium properties after the interaction within the uniform distribution statistics, since the uniform character is lost. It represents a severe shortcoming of the statistical ensemble from a methodological point of view, since closed systems can be always considered as the result of interaction among previously isolated systems. On the other hand this drawback introduces a further requirement of a different nature that can be used for the definition of a new statistical ensemble. In this work I intend to find and characterize a statistical ensemble for populations that overcomes the drawbacks of the uniform distribution of pure states. The invariance of the thermal state in the coupling of identical systems will be used as a guideline in the definition af a new probability distribution on populations. Such an ensemble for pure states, called Thermalization Resilient Ensemble, provides a convenient framework for treating the interactions between quantum systems, as long as the structure of the statistical distribution is preserved and the identification of thermodynamic properties is assured. In perspective it should be the privileged statistical ensemble to implement Quantum Dynamics Simulations. Once the average properties of the Thermalization Resilient Ensemble have been introduced, I will obtain a probability distribution on pure states with the use of a geometrical analysis on the Hilbert space. The surface elements of an ellipsoidal manifold will be related to the probability density on populations. As a matter of fact the explicit form of the probability distribution is a prerequisite in order to perform Quantum Dynamical Simulations. However the results obtained through the geometrical analysis cannot be easily extended to systems with unbounded energy spectrum and an alternative strategy has been developed. A scaling algorithm on the basis of the uniform statistical ensemble will be described and this allows a well defined sampling of a probability distribution with desired averages. In this framework I demonstrate the emergence of thermodynamic behavior in the limit of macroscopic systems. In the last part of the thesis I consider the dynamical features of the thermalization experiment. Two identical systems, initially at different temperature, will be brought in interaction and the analysis of the final equilibrium state will be performed for two different generic forms of the interaction Hamiltonian, highlighting how the statistical approach can be very useful in the definition of the equilibrium in complex quantum systems.
In a previous paper, we showed that the Hamilton equations of motion of a quantum particle are obtained as group velocities of the wave packet describing this particle only if the time dependent phase of a particle wave is proportional to the Lagrangian, not to the Hamiltonian as in a solution of the conventional Schrodinger equation. When a Lagrangian of relativistic form is considered, the wave packet of a quantum particle takes a physical form, with a finite spectrum of a cut off velocity (c). Based on a relativistic quantum principle, asserting the invariance of the time dependent phase for an arbitrary change of coordinates, we obtained the relativistic kinematics and dynamics, the electromagnetic field equations, the spin and the electromagnetic and gravitational interactions. When the Lagrangian is considered as a function of the Hamiltonian, we obtain a Schrodinger type equation with an additional term depending on the velocity and the momentum operator. Based on this equation, we investigate the dynamics of a relativistic quantum particle. In this framework, such a particle is described as a continuous distribution of conservative matter, according to the general theory of relativity. In an electromagnetic field, any time dependent phase variation is modified with a term proportional to a vector potential conjugated to the spatial coordinates and a scalar potential conjugated to time. However, this classical description tells us nothing about the structure of the physical world. Only Quantum Mechanics tells us something about the structure of this world. Namely, that this world is composed of species of identical quantum particles. On one hand, experimentally, it has been found that these particles are of a wavy nature. On the other hand, one could find that the simplest way to define a quantum particle is by a wave packet, with momenta conjugated to coordinates and energy conjugated to time Consider a quantum particle as a wave packet, and find that the group velocities in the coordinate and momentum spaces are in agreement with the Hamilton equations only when the Lagrangian is considered in the time dependent phases, instead of the Hamiltonian in the conventional forms of these waves as solutions of the Schrodinger equation. We define a relativistic quantum principle, and derive a wave equation for a relativistic quantum particle, the relativistic kinematics and dynamics of the particle waves, the Maxwell equations and the Lorentz force of a field interacting with the particle waves, the relativistic transform of such a field, and the spin as a characteristic of the particle waves. We consider a quantum particle as a distribution of conservative matter propagating according to the General Theory of Relativity. We obtain the dynamics of this matter in a gravitational field, the propagation in plane waves perpendicular to geodesic tracks, and equations of conservation. We describe the matter dynamics as a positively defined density and show that, according to the general theory of relativity, such a distribution can be conceive only as of a fragment of matter with a finite mass equal to a mass , as a characteristic of the matter dynamics, – the matter quantization. The group velocities of the Fourier conjugate representations in the coordinate and momentum spaces describe the dynamics of a quantum particle in agreement with the Hamiltonian equations. Under the action of an external (non-gravitational) field, the acceleration of the quantum matter has two components: 1) A component perpendicular to the velocity, given by the relativistic mechanical component of the time dependent phase, and 2) A component given by the additional field terms of this phase. A free quantum particle is described by a non-dispersing wave function , contrary to the solution of the Schrodinger equation. A coherent electromagnetic field, in resonance with a system of active quantum particles in a Fabry-Perot cavity, has a wave vector approximately proportional to the metric elements, as the resonance frequency is approximately constant – a gravitational wave can be detected by the transmission characteristics of an active Fabry-Perot cavity. In a constant gravitational field, a quantum particle undertakes a velocity and an acceleration, which, at the boundary of a black hole are null – absorption and evaporation processes at the boundary of a black hole arise only by gravitational perturbations. Generally, a quantum particle is described by a time-space volume, called graviton, with a spin 2, and a distribution of a specific matter in this volume, with a half-integer spin for Fermions and an integer spin for Bosons. A graviton Lagrangian is obtained as a curvature integral on a graviton volume, and a Hamiltonian tensor is obtained for the gravitational coordinates and velocities. In a gravitational field, the time space coordinates are deformed. In such a field, any plane wave remains perpendicular geodesic, while an additional acceleration is possible in the wave plane.
An explicit model allowing a unified description of microscopic and macroscopic systems is exhibited. First, a modified quantum dynamics for the description of macroscopic objects is constructed and it is shown that it forbids the occurrence of linear superpositions of states localized in far-away spatial regions and induces an evolution agreeing with classical mechanics. This dynamics also allows a description of the evolution in terms of trajectories. To set up a unified description of all physical phenomena, a modification of the dynamics, with respect to the standard Hamiltonian one, is then postulated also for microscopic systems. It is shown that one can consistently deduce from it the previously considered dynamics for the center of mass of macroscopic systems. Choosing in an appropriate way the parameters of the so-obtained model one can show that both the standard quantum theory for microscopic objects and the classical behavior for macroscopic objects can all be derived in a consistent way. In the case of a macroscopic system one can obtain, by means of appropriate approximations, a description of the evolution in terms of a phase-space density distribution obeying a Fokker-Planck diffusion equation. The model also provides the basis for a conceptually appealing description of quantum measurement.
Bohm theory is a formulation of Quantum Mechanics that characterises the state of a quantum system according to both the wave function, as in the conventional formulation, and the coordinates (positions) of all the particles that evolve in time drawing quantum continuous trajectories. Furthermore, a statistical ensemble of all the possible trajectories, raising from the impossibility to know the initial position of all the particles, establishes the exact correspondence with the traditional Quantum Mechanics. From a computational point of view, Bohm theory has found many applications in Chemical Physics especially to develop new methodologies for solving the Schrödinger equation and to address semi-classical approximations of Quantum Mechanics. From a theoretical point of view, the most appealing feature of Bohm theory is its capability to supply a conceptual map between the quantum formalism and our representation of what a chemical system is. Chemical systems are composed of molecules, but the same idea of molecule requires a specific arrangement in the space of particles, i.e., the nuclei of the atoms. The statistical description of conventional Quantum Mechanics on the basis of wave function alone is insufficient to establish a clear correspondence with such a picture of molecules. Indeed, chemists employ usually Classical Mechanics in order to overcome this drawback of the standard quantum theory. On the other hand, if the particles position is included in the quantum formalism, as Bohm theory does, the map can be defined in a self-consistent way. In other words, Bohm theory appears to be the suitable quantum framework to represent molecules and their motion. The chemical representation of molecular systems finds a natural correspondence with a single Bohm trajectory, since it is always implicitly assumed that molecular components have specific spatial position independently of our knowledge about it. Consequently, we develop a quantum method whose fundamental assumption is that a single Bohm trajectory, i.e., a quantum molecular trajectory, describes the molecular systems and the molecular motion correctly. First of all, we examine the correspondence between a single Bohm trajectory and the conventional Quantum Mechanics, without using the ensemble of trajectories. We verify that such a correspondence exists through numerical simulations and we prove formally that the statistical properties of a single Bohm trajectory explain the probabilistic description of Quantum Mechanics. Once the consistency of this original approach has been established, we investigate the predicted properties. For instance, we take into account the constants of motion (such as the energy) corresponding to the time evolution of the coordinates and the behaviour of simple chemical systems, e.g., the vibrational motion of single molecules interacting with a resonant field. In this way, unexpected features of the molecular motion are found. Secondly, we tackle the challenge of describing many components systems (like the chemical systems in ordinary conditions). As a matter of fact, the computation of the Bohm trajectory and of the wave function is extremely demanding. However, the statistical properties of the Bohm trajectory allow the derivation of stochastic theories for examining the dynamics of open quantum systems, i.e., few molecules (or few degrees of freedom) interacting with their environment (the other molecules). One of the developed stochastic methods correlates the dynamics of the reduced density matrix, for the degrees of freedom of interest, to the evolution of the corresponding Bohm coordinates. In other words, the Bohm equation, determining the set of all the particles velocities according to the full wave function, is replaced with a stochastic one that approximates the velocity of a subset of coordinates according to the reduced density matrix. In such a way, the quantum fluctuations induced by the environment are taken into account. The advantage of this method concerns its capability of describing quantum systems, including open quantum systems, in terms of a quantum trajectory. This could allow the understanding of the molecular motion during a spectroscopical experiment. The possibility of investigating reactive systems, such as conformational changes, is particularly interesting. As a matter of fact, chemical reactions can be completely characterised only through the particles motion and we define the suit- able quantum methodology providing a self-consistent description of the molecular motion.
The theory of conservative diffusion and its main applications are reviewed.A basic model for the theory is diffusion of a cold light gas in a warm heavy gas before relaxation when light gas remains cold and mean energy of its particles conserves.Unlike the Lorentz gas, where thermal energies of light and heavy atoms are equal, here the same order are their thermal speeds.Such conservative diffusion is described by two equationsthe Hamilton-Jacobi and continuity equations, nonlinear under the probability density.They can be linearized by introduction of a complex probability amplitude, transforming them to the Schrödinger equation where one must add not probabilities, but probability amplitudes of alternatives.Mean free path and the corresponding momentum determine an elementary phase volume and a diffusion coefficient.The theory predicts a number of quasiquantum effects in classical systems.The formalism of quantum mechanics thus describes a classical conservative diffusion and quantum mechanics is only a special case of such diffusion in the vacuum, when the elementary phase volume is equal to the Planck constant.A conservative thermodiffusion at nonzero temperature gradient is studied also.Its properties, such as decreasing of intensity of fluctuations of particles (including redshift of frequencies), drift of particles to colder region and their thermodiffusive acceleration, not depending on the mass of particles, are similar to properties of gravitation.This allows us to identify gravitation by thermodiffusion in the physical vacuum.In the diffusive picture fluctuations of energy-momentum of classical particles due to interaction with vacuum lead to increasing of their mean energy, which appears as quantum phenomena, while corresponding local decreasing of vacuum energy density reveals as gravitation.The diffusive treatment of quantum theory thus leads to the thermodiffusive treatment of gravitation too with natural synthesis of theories of both phenomena.Observable effects following from the new theory are discussed.
Three existing interpretations of quantum mechanics, given by Heisenberg, Bohm and Madelung, are examined to describe dissipative quantum systems as well. It is found that the Madelung quantum hydrodynamics is the only correct approach. A new stochastic reinterpretation of the quantum mechanics is proposed, which represents the microscopic face of the Madelung hydrodynamics. The main idea is that the vacuum fluctuates permanently, which explains the probabilistic character of the quantum mechanics. Thus, it is an objective theory independent of the human beings and their measurements. The effect of the thermal fluctuations in the surrounding is also accounted for via a heuristic Langevin equation with two random forces. Some statistical characteristics of these quantum and thermal noises are determined by reproducing known results for the system phase-space dynamics.