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arXiv:0812.1496 · Reviews of Modern Physics

Feshbach resonances in ultracold gases

Cheng Chin, Rudolf Grimm, Paul S. Julienne, Eite Tiesinga

Published Apr 29, 2010• 3,854 citations
arXivHTMLPDF

Abstract

Feshbach resonances are the essential tool to control the interaction between atoms in ultracold quantum gases. They have found numerous experimental applications, opening up the way to important breakthroughs. This review broadly covers the phenomenon of Feshbach resonances in ultracold gases and their main applications. This includes the theoretical background and models for the description of Feshbach resonances, the experimental methods to find and characterize the resonances, a discussion of the main properties of resonances in various atomic species and mixed atomic species systems, and an overview of key experiments with atomic Bose-Einstein condensates, degenerate Fermi gases, and ultracold molecules.

DOI
10.1103/revmodphys.82.1225

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Feshbach resonances are the essential tool to control the interaction between atoms in ultracold quantum gases. They have found numerous experimental applications, opening up the way to important breakthroughs. This review broadly covers the phenomenon of Feshbach resonances in ultracold gases and their main applications. This includes the theoretical background and models for the description of Feshbach resonances, the experimental methods to find and characterize the resonances, a discussion of the main properties of resonances in various atomic species and mixed atomic species systems, and an overview of key experiments with atomic Bose-Einstein condensates, degenerate Fermi gases, and ultracold molecules.
Besides the enormous opportunities offered by spectroscopy and atom interferometry, laser cooling has opened up the possibility of experimentally realizing and manipulating quantum degenerate gases: Bose–Einstein condensates and degenerate Fermionic systems. This chapter starts with an illustration of key experimental techniques, such as magnetic trapping, evaporative cooling, and Feshbach resonances. It then turns to the physics of atomic Bose–Einstein condensates, discussing their superfluid behaviour, their coherence properties, and their application to precise measurements. It also describes the experimental investigation of ultracold Fermi gases and fermionic superfluidity, as well as ongoing research into ultracold polar molecules.
In this habilitation-thesis a collection of 14 experiments is presented. In these experiments we have developed and used novel techniques to control ultracold gases on the quantum level. In brief, Bose-Einstein condensates (BEC) and degenerate Fermi gases of laser-cooled alkali atoms are subjected to specially designed optical and magnetic fields. The fields influence in a coherent way the behavior, properties and dynamics of the gases. On this basis we developed tools to prepare, coherently manipulate, and analyze pre-defined quantum states. With this high level of control, it was possible to investigate interesting physics phenomena, and we were able to achieve several breakthroughs in the field of ultracold atoms. Highlights of our experimental results include the demonstration of phase engineering of a BEC wavefunction where we created solitons in a BEC and studied their propagation. In another experiment we constructed a spatially resolved matter wave interferometer with which we mapped out the phase distribution on a condensate. Illuminating the BEC with a periodic pattern, i.e. an optical lattice, allowed us to study solid states physics phenomena. In a second set of experiments we demonstrated optically tuning of the interaction between atoms with optical Feshbach resonances. Employing either magnetically tunable Feshbach resonances or laser radiation, we were able to produce ground state molecules in well defined quantum states. This led to the production of the first molecular BEC. By tuning the coupling of atom pairs in a Fermi gas of atoms, we could for the first time investigate the so-called BEC-BCS crossover which describes the continuous change from a BEC superfluid to a Bardeen-Cooper Schrieffer (BCS) superfluid. Due to the excellent control on the quantum level, the developed cold atom techniques open up intriguing prospects for future applications and experiments. They represent a general tool box to investigate fundamental physical phenomena in a pure and undisturbed environment. In the future, cold atoms might serve as a testing ground for fundamental theories or as quantum simulators for complex systems.
The main topic of these lectures is the physics of quantum degenerate atomic Fermi gases both under uniform confinement and in harmonic traps. To begin with, a general introduction on ideal Fermi gases is proposed. This "academic" limit is relevant in experiments where ultracold fermionic atoms are all polarized in a single spin state: the low atom momenta together with the fermionic nature of the atoms forbid atomic s-wave scattering and the atoms can be considered as free. Interactions are then introduced for the case of a gas with two spin components. Interactions can be tuned via Feshbach resonances and control the microscopic features of the superfluid phase, ranging from the BCS limit (formation of Cooper pairs) to the BEC limit (Bose-Einstein condensation of dimers). Various theoretical approaches for the description of the BCS-BEC crossover and their predictions in comparison with the experimental results are discussed.
The physics of quantum degenerate atomic Fermi gases in uniform as well as in harmonically trapped configurations is reviewed from a theoretical perspective. Emphasis is given to the effect of interactions that play a crucial role, bringing the gas into a superfluid phase at low temperature. In these dilute systems, interactions are characterized by a single parameter, the sss-wave scattering length, whose value can be tuned using an external magnetic field near a broad Feshbach resonance. The BCS limit of ordinary Fermi superfluidity, the Bose-Einstein condensation (BEC) of dimers, and the unitary limit of large scattering length are important regimes exhibited by interacting Fermi gases. In particular, the BEC and the unitary regimes are characterized by a high value of the superfluid critical temperature, on the order of the Fermi temperature. Different physical properties are discussed, including the density profiles and the energy of the ground-state configurations, the momentum distribution, the fraction of condensed pairs, collective oscillations and pair-breaking effects, the expansion of the gas, the main thermodynamic properties, the behavior in the presence of optical lattices, and the signatures of superfluidity, such as the existence of quantized vortices, the quenching of the moment of inertia, and the consequences of spin polarization. Various theoretical approaches are considered, ranging from the mean-field description of the BCS-BEC crossover to nonperturbative methods based on quantum Monte Carlo techniques. A major goal of the review is to compare theoretical predictions with available experimental results.
The study of ultracold atomic Fermi gases is a rapidly exploding subject which is defining new directions in condensed matter and atomic physics. Quite generally what makes these gases so important is their remarkable tunability and controllability. Using a Feshbach resonance one can tune the attractive two-body interactions from weak to strong and thereby make a smooth crossover from a BCS superfluid of Cooper pairs to a Bose-Einstein condensed superfluid. Furthermore, one can tune the population of the two spin states, allowing observation of exotic spin-polarized superfluids, such as the Fulde Ferrell Larkin Ovchinnikov (FFLO) phase. A wide array of powerful characterization tools, which often have direct condensed matter analogues, are available to the experimenter. In this Chapter, we present a general review of the status of these Fermi gases with the aim of communicating the excitement and great potential of the field.
Understanding and controlling interactions of ultracold molecules is a cornerstone of quantum chemistry. While the laboratory creation of degenerate molecular gases comprised of bosonic atoms has unlocked powerful platforms for quantum simulation, progress is limited by the absence of a robust theoretical framework for characterizing intermolecular interactions. This is in stark contrast to the situation for Fermi gases. In this Letter, we present such a framework providing universal expressions for these molecular scattering lengths as functions of experimentally measurable quantities. Our discoveries are crucial for understanding molecular condensate formation. Calculations of the compressibility reveal that a sign change in such molecular scattering lengths is directly correlated with the instability of these condensates. These results offer fresh insight with broad applications for atomic, molecular, and condensed matter physics, as well as quantum chemistry.