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arXiv:0811.1049 · Annals of Physics

Valence-bond states: Link models

E. Rico, R. Hübener, Simone Montangero, Niall Moran, Bogdan-Constantin Pîrvu, Jiří Vala, Hans J. Briegel

Published Jun 17, 2009• 3 citations
arXivHTMLPDF
DOI
10.1016/j.aop.2009.06.001

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The ground state of an antiferromagnetic Heisenberg model on L X L clusters joined by a single bond and balanced Bethe clusters are investigated with quantum Monte Carlo and modified spin-wave theory. The improved Monte Carlo method of Sandvik and Evertz is used and the observables include valence bond and loop valence bond observables introduced by Lin and Sandvik as well as the valence bond entropy and the second Renyi entropy. For the bisecting of the Bethe cluster, in disagreement with our previous results and in agreement with modified spin-wave theory, the valence loop entropy and the second Renyi entropy scale as the logarithm of the number of sites in the cluster. For bisecting the L X L - L X L clusters, the valence bond entropy scales as L, however, the loop entropy and the entanglement entropy scale as ln(L). For the entanglement entropy, the coefficient of the logarithm, the number of Goldstone modes/2, is universal and is the analogue of the sub leading term of a LXL cluster. This result was substantiated by a modified spin-wave theory calculation for the ferromagnetic X-Y model. Taken together, the calculations suggest that linking high entanglement objects will not generate much more entanglement. As a consequence, simulating the ground state of clusters joined together by a few bonds should not be much more difficult than simulating the ground state of a single cluster.
In this work we investigate the supersymmetric version of the valence bond solid (SVBS) state. In one dimension, the SVBS states continuously interpolate between the valence bond states for integer and half-integer spin chains, and they generally describe superconducting valence bond liquid states. Spin and superconducting correlation functions can be computed exactly for these states and their correlation lengths are equal at the supersymmetric point. In higher dimensions, the wave function for the SVBS states can describe resonating valence bond states. The SVBS states for the spin models are shown to be precisely analogous to the bosonic Pfaffian states of the quantum Hall effect. We also give microscopic Hamiltonians for which the SVBS state is the exact ground state.
The set of valence-bond states --- states in which localized spin-1/2 particles are correlated in singlet pairs said to be connected by valence bonds --- provides a useful basis for visualizing singlet ground states of quantum spin systems. For example, the ground state of the uniform one-dimensional nearest-neighbor spin-1/2 antiferromagnetic (AFM) Heisenberg model (the prototypical spin-liquid state) can be viewed as a strongly fluctuating liquid of valence bonds with a power-law length distribution. This intuitive picture directly reflects the long-range spin correlations in this state, as well as the existence of gapless excitations created by breaking long bonds. Valence-bond states also play a key role in describing the physics of random spin-1/2 AFM Heisenberg chains. For these systems, it was shown by Fisher, using a real space renormalization group analysis, that on long-length scales the ground state is described by a single valence-bond state known as a random singlet state. This single valence-bond state should be viewed as a caricature of the true ground state, which will certainly exhibit bond fluctuations on short-length scales. In valence-bond Monte Carlo (VBMC) simulations valence-bond states are used to stochastically sample singlet ground states of quantum spin systems. One of the appealing features of VBMC is that if one imagines viewing the sampled valence-bond states over many Monte Carlo time steps the resulting ''movie" would correspond closely to the intuitive resonating valence bond picture described above. For random Heisenberg chains (and related models) VBMC should therefore provide a useful method for directly studying the phenomenon of random singlet formation on long-length scales, while at the same time capturing the short-range fluctuations which will always be present. In this dissertation I present results of VBMC studies for a class of models which include the uniform and random spin-1/2 AFM Heisenberg chains, as well as models describing chains of interacting non-Abelian quasiparticles --- exotic quasiparticles conjectured to exist in certain fractional quantum Hall states. In addition to numerically computing and analyzing the so-called valence-bond entanglement scaling in these models, I introduce a new quantity which I refer to as the valence-bond fluctuation (the central new result and the main contribution of this dissertation). It is shown that this quantity, which is easy to compute in valence-bond Monte Carlo, provides a direct signature of random singlet phase formation by essentially allowing one to directly ''see" the ''locking" of the ground state into a particular valence-bond state on long-length scales. A detailed scaling analysis of this new quantity is then used to extract the dependence of the fluctuation length scale on disorder strength. Where possible, the results are compared to previous numerical and analytic work on the relevant models.