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arXiv:0809.3474

Quantum Impurity Problems in Condensed Matter Physics

Ian K. Affleck

Published Sep 20, 2008• 35 citations
arXivHTMLPDF

Abstract

Impurities are ubiquitous in condensed matter. Boundary Conformal Field Theory (BCFT) provides a powerful method to study a localized quantum impurity interacting with a gapless continuum of excitations. The results can also be implied to nanoscopic devices like quantum dots. In these lecture notes, I review this field, including the following topics: I. General Renormalization Group (RG) framework for quantum impurity problems: example of simplest Kondo model II. Multi-channel Kondo model III. Quantum Dots: experimental realizations of one and two channel Kondo models IV. Impurities in Luttinger liquids: point contact in a quantum wire V. Quantum impurity entanglement entropy VI. Y-junctions of Luttinger liquids VII. Boundary condition changing operators and the X-ray edge problem.

DOI
10.48550/arxiv.0809.3474

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Impurities are ubiquitous in condensed matter. Boundary Conformal Field Theory (BCFT) provides a powerful method to study a localized quantum impurity interacting with a gapless continuum of excitations. The results can also be implied to nanoscopic devices like quantum dots. In these lecture notes, I review this field, including the following topics: I. General Renormalization Group (RG) framework for quantum impurity problems: example of simplest Kondo model II. Multi-channel Kondo model III. Quantum Dots: experimental realizations of one and two channel Kondo models IV. Impurities in Luttinger liquids: point contact in a quantum wire V. Quantum impurity entanglement entropy VI. Y-junctions of Luttinger liquids VII. Boundary condition changing operators and the X-ray edge problem.
We study different aspects of integrable boundary quantum field theories, focusing mostly on the ``boundary sine-Gordon model'' and its applications to condensed matter physics. The first part of the review deals with formal problems. We analyze the classical limit and perform semi-classical quantization. We show that the non-relativistic limit corresponds to the Calogero-Moser model with a boundary potential. We construct a lattice regularization of the problem via the XXZ chain. We classify boundary bound states. We generalize the Destri de Vega method to compute the ground state energy of the theory on a finite interval. The second part deals with some applications to condensed matter physics. We show how to compute analytically time and space dependent correlations in one-dimensional quantum integrable systems with an impurity. Our approach is based on a description of these systems in terms of massless scattering of quasiparticles. Correlators follow then from matrix elements of local operators between multiparticle states -- the massless form-factors. Although, in general an infinite sum of these form-factors has to be considered, we find that for the current, spin and energy operators only a few (two or three) are necessary to obtain an accuracy of more than 1\%. Our results hold for arbitrary impurity strength, in contrary to the perturbative expansions in the coupling constants. As an example, we compute the frequency dependent condunctance, at zero temperature, in a Luttinger liquid with an impurity, and also discuss the susceptibility in the Kondo model and the time-dependent properties of the two-state problem with dissipation.
A new, general approach to finding exact solutions of Quantum Impurity Problems is reviewed, in which a local quantum mechanical degree of freedom is coupled to an extended variable, having gapless excitations. The principle ideas, using Conformal Field Theory techniques, are demonstrated in the example of the Multi-Channel Kondo effect, which exhibits unusual non-Fermi-liquid behavior at low temperatures and which appears to be relevant for Heavy Fermion Materials. In particular, static and dynamic Green's functions as well as transport and pairing properties are calculated exactly at low temperatures. Quantum Impurity Problems provide realizations of non-trivial, fully interacting Conformal Field Theories.
Quantum entanglement between an impurity and its environment is expected to be central in quantum impurity problems. We develop a method to compute the entanglement in spin-1/2 impurity problems, based on the entanglement negativity and the boundary conformal field theory (BCFT). Using the method, we study the thermal decay of the entanglement in the multichannel Kondo effects. At zero temperature, the entanglement has the maximal value independent of the number of the screening channels. At low temperature, the entanglement exhibits a power-law thermal decay. The power-law exponent equals two times of the scaling dimension of the BCFT boundary operator describing the impurity spin, and it is attributed to the energy-dependent scaling behavior of the entanglement in energy eigenstates. These agree with numerical renormalization group results, unveiling quantum coherence inside the Kondo screening length.
The boundary conformal field theory approach to quantum impurity problems is used to study the Fermi edge singularity, occurring in the X-ray adsorption probability. The deep-hole creation operator, in the effective low-energy theory, changes the boundary condition on the conduction electrons. By a conformal mapping, the dimension of such an operator is related to the ground-state energy for a finite system with different boundary conditions at the two ends. The Fermi edge singularity is solved, using this method, for the Luttinger liquid including backscattering and for the multi-channel Kondo problem.
The quantum physics of one dimensional systems exhibits many remarkable and exotic physical phenomena. These are the result of the strong correlations which exist in such systems due to the reduced dimensionality and in many cases can be described by Luttinger Liquid theory. Likewise quantum impurity systems, where a bath of particles couples to the same impurity, exhibit well known non perturbative phenomena like the Kondo effect. In this thesis we study the physics of quantum impurities in interacting environments - the intersection of these two areas. Such Luttinger-impurity systems can be realized experimentally in a range of different settings from quantum wires and carbon nano tubes to edges of fractional quantum hall systems and cold atom gases. We show that many of the models used to describe these experiments are integrable and can be studied by means of the Bethe Ansatz. This powerful and exact method provides us with the exact eigenstates and energy levels of the model Hamiltonian. The models considered include two which describe a Lutttinger liquid coupled to a back scattering impurity, the Kane-Fisher and weak tunnelling model as well as Luttinger liquids coupled a quantum dot in various geometries: at the boundary, sidecoupled and embedded. To incorporate both the backscattering nature of the impurities and the interacting bulk particles a new formulation of the Bethe Ansatz is developed and implemented. The eigenstates and spectra of the models are found and used to investigate their ground state and thermodynamic properties.