A general prescription for the treatment of constrained quantum motion is outlined. We consider in particular constraints defined by algebraic submanifolds of the quantum state space. The resulting formalism is applied to obtain solutions to the constrained dynamics of systems of multiple spin particles. When the motion is constrained to a certain product space containing all of the energy eigenstates, the dynamics thus obtained are quasi-unitary in the sense that the equations of motion take a form identical to that of unitary motion, but with different boundary conditions. When the constrained subspace is a product space of disentangled states, the associated motion is more intricate. Nevertheless, the equations of motion satisfied by the dynamical variables are obtained in closed form.
A framework for deriving equations of motion for constrained quantum systems is introduced and a procedure for its implementation is outlined. In special cases, the proposed new method, which takes advantage of the fact that the space of pure states in quantum mechanics has both a symplectic structure and a metric structure, reduces to a quantum analogue of the Dirac theory of constraints in classical mechanics. Explicit examples involving spin- particles are worked out in detail: in the first example, our approach coincides with a quantum version of the Dirac formalism, while the second example illustrates how a situation that cannot be treated by Dirac's approach can nevertheless be dealt with in the present scheme.
A framework for deriving equations of motion for constrained quantum systems is introduced and a procedure for its implementation is outlined. In special cases, the proposed new method, which takes advantage of the fact that the space of pure states in quantum mechanics has both a symplectic structure and a metric structure, reduces to a quantum analogue of the Dirac theory of constraints in classical mechanics. Explicit examples involving spin- particles are worked out in detail: in the first example, our approach coincides with a quantum version of the Dirac formalism, while the second example illustrates how a situation that cannot be treated by Dirac's approach can nevertheless be dealt with in the present scheme.
We discuss the introduction of constraints in a system of n noninteracting particles which obey the laws of nonrelativistic quantum mechanics. In this paper the particles are first thought of as being unconstrained (described by the
3n Cartesian coordinates of a flat space
R), but subject to an external potential
V which, in a certian suitable limit, forces the system to remain in a curved subspace
V of
R. This idea was already employed in a previous work where we have discussed the motion of one constrained particle. It was then shown that in order to obtain a meaningful result the particle wave function should be "uniformly compressed" into a surface (or curve), avoiding, in this way, the tangential forces which correspond to the dissipative constraints of classical mechanics. The resulting Schr\"odinger equation could then be separated in such a way that the part which contained the surface (or curve) variables was independent of the potential
V employed in the constraining process. In the present paper we show that this procedure cannot be carried out for all subspaces
V of
R in the case of a many-particle system, unless
V satisfies a certain geometrical condition. The many-particle Schr\"odinger equation (as was already the case of the one-particle systems) contains, besides the kinetic energy term, potentials which are not bending invariants, that is, cannot be obtained from the metric tensor
gij of
V or its derivatives. This gives rise to different Schr\"odinger equations for isometric subspaces, in striking contrast with the usual quantization procedures which start from the classical Lagrangian of the constrained system.
An effective formalism for quantum constrained systems is presented which allows manageable derivations of solutions and observables, including a treatment of physical reality conditions without requiring full knowledge of the physical inner product. Instead of a state equation from a constraint operator, an infinite system of constraint functions on the quantum phase space of expectation values and moments of states is used. The examples of linear constraints as well as the free non-relativistic particle in parametrized form illustrate how standard problems of constrained systems can be dealt with in this framework.
An approach is formulated to the problem of obtaining approximate solutions to many-body quantum mechanics. The starting point is the representation of quantum mechanics as Hamiltonian mechanics on a symplectic manifold (phase space). It is shown that Dirac's variation of an action integral provides a natural mechanism for constraining the dynamics to symplectic submanifolds and gives rise to a hierarchy of approximate many-body theories of which Hartree-Fock, random-phase approximation, time-dependent Hartree-Fock, and the double commutator equations of motion formalism are special cases.