The emergence of the laws of thermodynamics from the laws of quantum mechanics is an unresolved issue. The generation of the third law of thermodynamics from quantum dynamics is analysed. The scaling of the optimal cooling power of a reciprocating quantum refrigerator is sought as a function of the cold bath temperature as T c →0. The working medium consists of noninteracting particles in a harmonic potential. Two closed-form solutions of the refrigeration cycle are analyzed, and compared to a numerical optimization scheme, focusing on cooling toward zero temperature. The optimal cycle is characterized by linear relations between the heat extracted from the cold bath, the energy level spacing of the working medium and the temperature. The scaling of the optimal cooling rate is found to be proportional to T c 3/2 giving a dynamical interpretation to the third law of thermodynamics.
The emergence of the laws of thermodynamics from the laws of quantum mechanics is an unresolved issue. The generation of the third law of thermodynamics from quantum dynamics is analysed. The scaling of the optimal cooling power of a reciprocating quantum refrigerator is sought as a function of the cold bath temperature as T c →0. The working medium consists of noninteracting particles in a harmonic potential. Two closed-form solutions of the refrigeration cycle are analyzed, and compared to a numerical optimization scheme, focusing on cooling toward zero temperature. The optimal cycle is characterized by linear relations between the heat extracted from the cold bath, the energy level spacing of the working medium and the temperature. The scaling of the optimal cooling rate is found to be proportional to T c 3/2 giving a dynamical interpretation to the third law of thermodynamics.
One of the formulations of the third laws of thermodynamics is that a processes become more isentropic as one approaches the absolute zero temperatures. We examine this prediction by studying an operating model of a quantum refrigerator pumping heat from a cold to a hot reservoir. The working medium consists of a gas of noninteracting harmonic oscillators. The model can be solved in closed form in the quasi-static limit or numerically for general conditions. It is found that the isentropic limit for Tc → 0 is approached only on the expansion segment of the refrigeration cycle. The scaling of the cooling rate with temperature is shown to be consistent with the second law of thermodynamics. This scaling is also consistent with the unattainability principle which is an alternative formulation of the third law of thermodynamics.
The rate of temperature decrease of a cooled quantum bath is studied as its temperature is reduced to absolute zero. The third law of thermodynamics is then quantified dynamically by evaluating the characteristic exponent ζ of the cooling process dT(t)/dt∼-T^{ζ} when approaching absolute zero, T→0. A continuous model of a quantum refrigerator is employed consisting of a working medium composed either by two coupled harmonic oscillators or two coupled two-level systems. The refrigerator is a nonlinear device merging three currents from three heat baths: a cold bath to be cooled, a hot bath as an entropy sink, and a driving bath which is the source of cooling power. A heat-driven refrigerator (absorption refrigerator) is compared to a power-driven refrigerator. When optimized, both cases lead to the same exponent ζ, showing a lack of dependence on the form of the working medium and the characteristics of the drivers. The characteristic exponent is therefore determined by the properties of the cold reservoir and its interaction with the system. Two generic heat bath models are considered: a bath composed of harmonic oscillators and a bath composed of ideal Bose/Fermi gas. The restrictions on the interaction Hamiltonian imposed by the third law are discussed. In the Appendices, the theory of periodically driven open systems and its implication for thermodynamics are outlined.
The study of nanoscopic thermal devices attracts an increasing attention, not only because of their key role in understanding the emergence of thermodynamics from quantum theory, but also for the potential use of quantum-mechanical thermal cycles, especially refrigerators, in quantum technologies. This thesis, is devoted to the performance optimization of autonomous (heat-driven) refrigerators. For a quantum refrigerator, one has a full microscopic description of the simple system serving as a working medium, and of its interaction with the external heat baths. This enables a consistent `finite-time? thermodynamic analysis, not relying on any phenomenological assumptions about the leading sources of irreversibility, and allows to establish arguably general performance bounds, essential to benchmark the operation of realistic devices. In particular, tight and model-independent upper bounds for the coefficient of performance at maximum power, are derived here for a class of strongly coupled refrigerators, and seen to hold more generally for other types of heat and power-driven cycles. Remarkably, these ultimate limitations only depend on the particulars of the system-baths interaction at the interface with the object to be cooled. Strategies might be then defined so as to saturate those limits: It is shown how the working medium of the refrigerator may be, for instance, scaled up into a parallel multi-stage configuration, resembling that of macroscopic multi-effect absorption chillers, as a means to increase its cooling power. Similarly, by applying reservoir engineering techniques on selected transitions between the energy states of the working medium, one can mimic exploitable non-equilibrium fluctuations in the baths, capable of boosting the overall power and COP beyond what would be otherwise allowed by the second law of thermodynamics. In this way, heat-driven chillers could be set to compete on a equal footing with the best power-driven refrigerators.
The second and third laws of thermodynamics can be used to establish a fundamental bound for the maximum possible cooling rate in approaching the absolute zero of temperature. In modeling the behavior of the molecular refrigerators geared toward attaining ultralow temperatures, only quantum mechanical, as opposed to classical physics, models can be admissible. As a simple model, we analyze a three-level quantum refrigerator, and in particular its irreversible thermodynamic performance as absolute zero is approached.
A quantum absorption refrigerator driven by noise is studied with the purpose of determining the limitations of cooling to absolute zero. The model consists of a working medium coupled simultaneously to hot, cold, and noise baths. Explicit expressions for the cooling power are obtained for Gaussian and Poisson white noise. The quantum model is consistent with the first and second laws of thermodynamics. The third law is quantified; the cooling power J(c) vanishes as J(c) ∝ T(c)(α), when T(c)→0, where α=d+1 for dissipation by emission and absorption of quanta described by a linear coupling to a thermal bosonic field, where d is the dimension of the bath.
A reciprocating quantum refrigerator is studied with the purpose of determining the limitations of cooling to absolute zero. We find that if the energy spectrum of the working medium possesses an uncontrollable gap, then there is a minimum achievable temperature above zero. Such a gap, combined with a negligible amount of noise, prevents adiabatic following during the demagnetization stage which is the necessary condition for reaching Tc→0. The refrigerator is based on an Otto cycle where the working medium is an interacting spin system with an energy gap. For this system the external control Hamiltonian does not commute with the internal interaction. As a result during the demagnetization and magnetization segments of the operating cycle the system cannot follow adiabatically the temporal change in the energy levels. We connect the nonadiabatic dynamics to quantum friction. An adiabatic measure is defined characterizing the rate of change of the Hamiltonian. Closed form solutions are found for a constant adiabatic measure for all the cycle segments. We have identified a family of quantized frictionless cycles with increasing cycle times. These cycles minimize the entropy production. Such frictionless cycles are able to cool to Tc=0. External noise on the controls eliminates these frictionless cycles. The influence of phase and amplitude noise on the demagnetization and magnetization segments is explicitly derived. An extensive numerical study of optimal cooling cycles was carried out which showed that at sufficiently low temperature the noise always dominates restricting the minimum temperature.