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arXiv:0807.3516 · Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences

Phase transition in space: how far does a symmetry bend before it breaks?

Wojciech H Zurek, Uwe Dorner

Published Jun 5, 2008• 42 citations
arXivHTMLPDF

Abstract

We extend the theory of symmetry-breaking dynamics in non-equilibrium second-order phase transitions known as the Kibble-Zurek mechanism (KZM) to transitions where the change of phase occurs not in time but in space. This can be due to a time-independent spatial variation of a field that imposes a phase with one symmetry to the left of where it attains critical value, while allowing spontaneous symmetry breaking to the right of that critical borderline. Topological defects need not form in such a situation. We show, however, that the size, in space, of the 'scar' over which the order parameter adjusts as it 'bends' interpolating between the phases with different symmetries follows from a KZM-like approach. As we illustrate on the example of a transverse quantum Ising model, in quantum phase transitions this spatial scale--the size of the scar--is directly reflected in the energy spectrum of the system: in particular, it determines the size of the energy gap.

DOI
10.1098/rsta.2008.0069

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We extend the theory of symmetry-breaking dynamics in non-equilibrium second-order phase transitions known as the Kibble-Zurek mechanism (KZM) to transitions where the change of phase occurs not in time but in space. This can be due to a time-independent spatial variation of a field that imposes a phase with one symmetry to the left of where it attains critical value, while allowing spontaneous symmetry breaking to the right of that critical borderline. Topological defects need not form in such a situation. We show, however, that the size, in space, of the 'scar' over which the order parameter adjusts as it 'bends' interpolating between the phases with different symmetries follows from a KZM-like approach. As we illustrate on the example of a transverse quantum Ising model, in quantum phase transitions this spatial scale--the size of the scar--is directly reflected in the energy spectrum of the system: in particular, it determines the size of the energy gap.
The Kibble-Zurek mechanism (KZM) successfully predicts the density of topological defects deposited by the phase transitions, but it is not clear why. Its key conjecture is that, near the critical point of the second-order phase transition, critical slowing down will result in a period when the system is too sluggish to follow the potential that is changing faster than its reaction time. The correlation length at the freeze-out instant t^\hat tt^ when the order parameter catches up with the post-transition broken symmetry configuration is then decisive, determining when the mosaic of broken symmetry domains locks in topological defects. To understand why the KZM works so well we analyze Landau-Ginzburg model and show why temporal evolution of the order parameter plays such a key role. The analytical solutions we obtain suggest novel, hitherto unexplored, experimentally accessible observables that can shed light on symmetry breaking dynamics while testing the conjecture on which the KZM is based.
The formation of topological defects in second-order phase transitions can be investigated by solving partial differential equations for the evolution of the order parameter in space and time, such as the Langevin equation. We demonstrate that the ordinary differential equations governing either the temporal or spatial dependence in the Langevin equation provide surprisingly substantial insights into the dynamics of the phase transition. The temporal evolution of the order parameter predicts the essence of the adiabatic-impulse scenario, including the scaling of the freeze-out time, which is crucial to the Kibble-Zurek mechanism (KZM). In particular, Bernoulli differential equations that arise in the overdamped case can be solved analytically. The spatial part of the evolution, in turn, leads to the characteristic size of domains that choose the same broken symmetry. Apart from the fundamental insights into the KZM, this finding enables the exploration of Kibble-Zurek scaling using ordinary differential equations over a large range of quench timescales, which would otherwise be difficult to achieve with numerical simulations of the full partial differential equations.
Universal scaling laws govern the density of topological defects generated while crossing an equilibrium continuous phase transition. The Kibble-Zurek mechanism (KZM) predicts the dependence on the quench time for slow quenches. By contrast, for fast quenches, the defect density scales universally with the amplitude of the quench. We show that universal scaling laws apply to dynamic phase transitions driven by an oscillating external field. The difference in the energy response of the system to a periodic potential field leads to energy absorption, spontaneous breaking of symmetry, and its restoration. We verify the associated universal scaling laws, providing evidence that the critical behavior of nonequilibrium phase transitions can be described by time-average critical exponents combined with the KZM. Our results demonstrate that the universality of critical dynamics extends beyond equilibrium criticality, facilitating the understanding of complex nonequilibrium systems.
The crossing of a continuous phase transition results in the formation of topological defects with a density predicted by the Kibble-Zurek mechanism (KZM). We characterize the spatial distribution of pointlike topological defects in the resulting nonequilibrium state and model it using a Poisson point process in arbitrary spatial dimensions with KZM density. Numerical simulations in a one-dimensional ${\ensuremath{\phi}}^{4}$ theory unveil short-distance defect-defect corrections stemming from the kink excluded volume, while in two spatial dimensions, our model accurately describes the vortex spacing distribution in a strongly coupled superconductor indicating the suppression of defect-defect spatial correlations.
In the course of a nonequilibrium continuous phase transition, the dynamics ceases to be adiabatic in the vicinity of the critical point as a result of the critical slowing down (the divergence of the relaxation time in the neighborhood of the critical point). This enforces a local choice of the broken symmetry and can lead to the formation of topological defects. The Kibble–Zurek mechanism (KZM) was developed to describe the associated nonequilibrium dynamics and to estimate the density of defects as a function of the quench rate through the transition. During recent years, several new experiments investigated the formation of defects in phase transitions induced by a quench both in classical and quantum mechanical systems. At the same time, some established results were called into question. We review and analyze the Kibble–Zurek mechanism focusing in particular on this surge of activity, and suggest possible directions for further progress.
When a system is driven across a quantum critical point at a constant rate, its evolution must become nonadiabatic as the relaxation time $\ensuremath{\tau}$ diverges at the critical point. According to the Kibble-Zurek mechanism (KZM), the emerging post-transition excited state is characterized by a finite correlation length $\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{\ensuremath{\xi}}$ set at the time $\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{t}=\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{\ensuremath{\tau}}$ when the critical slowing down makes it impossible for the system to relax to the equilibrium defined by changing parameters. This observation naturally suggests a dynamical scaling similar to renormalization familiar from the equilibrium critical phenomena. We provide evidence for such KZM-inspired spatiotemporal scaling by investigating an exact solution of the transverse field quantum Ising chain in the thermodynamic limit.