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arXiv:0803.3277 · Physical Review A

Virial theorems for trapped cold atoms

Félix Werner

Published Aug 1, 2008• 75 citations
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Abstract

We present a general virial theorem for quantum particles with arbitrary zero-range or finite-range interactions in an arbitrary external potential. We deduce virial theorems for several situations relevant to trapped cold atoms: zero-range interactions with and without Efimov effect, hard spheres, narrow Feshbach resonances, and finite-range interactions. If the scattering length $a$ is varied adiabatically in a two-component Fermi gas, we find that the trapping potential energy as a function of $1∕a$ has an inflexion point at unitarity.

DOI
10.1103/physreva.78.025601

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We present a general virial theorem for quantum particles with arbitrary zero-range or finite-range interactions in an arbitrary external potential. We deduce virial theorems for several situations relevant to trapped cold atoms: zero-range interactions with and without Efimov effect, hard spheres, narrow Feshbach resonances, and finite-range interactions. If the scattering length aaa is varied adiabatically in a two-component Fermi gas, we find that the trapping potential energy as a function of 1∕a1∕a1∕a has an inflexion point at unitarity.
Optically-trapped two-component Fermi gases near a broad Feshbach resonance exhibit universal thermodynamics, where the properties of the gas are independent of the details of the two-body scattering interactions. We present a global proof that such a universal gas obeys the virial theorem for {\it any} trapping potential UUU and any spin mixture, without assuming either the local density approximation or harmonic confinement. The total energy of the gas is given in scale invariant form by E=E=E=, where εεε is an {\it arbitrary} energy scale in terms of which all length and energy scales that appear in the confining potential are written. This result enables model-independent energy measurement in traps that are anharmonic as well as anisotropic by observing only the cloud profile, and provides a consistency check for many-body calculations in the universal regime.
Optically trapped two-component Fermi gases near a broad Feshbach resonance exhibit universal thermodynamics, where the properties of the gas are independent of the details of the two-body scattering interactions. We show that the measured cloud profiles of both species determine the total energy of universal gases for any trapping potential UUU and any spin mixture, without assuming either the local density approximation or harmonic confinement. A global proof of the virial theorem yields the total energy of the gas at all temperatures in the scale-invariant form $E=⟨ϵ\ensuremath{\partial}U/\ensuremath{\partial}ϵ⟩$, where ϵϵϵ is an arbitrary energy scale in terms of which all length and energy scales that appear in the confining potential are written. This result enables model-independent energy measurement in any trap by observing only the cloud profiles, and provides a consistency check for many-body calculations in the universal regime.
We consider mass-imbalanced two-component Fermi gases for which the unequal-mass atoms interact via a zero-range model potential with a diverging sss-wave scattering length as{a}_{s}as​, that is, with 1/as=01/{a}_{s}=01/as​=0. The high-temperature thermodynamics of the harmonically trapped and homogeneous systems are examined using a virial expansion approach up to third order in the fugacity. We find that the universal part of the third-order virial coefficient associated with two light atoms and one heavy atom is negative, while that associated with two heavy and one light atom changes sign from negative to positive as the mass ratio $\ensuremath{\kappa}$ increases and diverges when Efimov physics sets in at $\ensuremath{\kappa}=13.61$. By examining the Helmholtz free energy, we find that the equilibrium polarization of the trapped and homogeneous systems is 0 for $\ensuremath{\kappa}=1$, but finite for $\ensuremath{\kappa}\ensuremath{\ne}1$ (with a majority of heavy particles). Compared to the equilibrium polarization of the noninteracting system, the equilibrium polarization at unitarity is increased for the trapped system and decreased for the homogeneous system. We find that unequal-mass Fermi gases are stable for all polarizations.
We review some unresolved theoretical issues in three-dimensional two-component Fermi gases, drawing on recent experiments on cold atoms in immaterial traps close to a magnetic Feshbach resonance. We distinguish successively (i) the open questions arising in the few-body problem with Wigner-Bethe-Peierls contact interactions - essentially the stability of the gas with respect to the Efimov effect and the calculation of the cluster (or virial) coefficients, (ii) those arising in the effective low-energy theory of Landau and Khalatnikov quantum hydrodynamics - essentially the damping of phonon modes and the coherence time of the condensate of pairs, and finally (iii) questions requiring a complete, microscopic solution of the many-body problem, such as the specific properties of the acoustic excitation branch (Goldstone) of the condensate of pairs, or its collective excitation branch (Higgs) in the broken-pair continuum.
We theoretically investigate the high-temperature thermodynamics of a harmonically trapped Fermi gas across a narrow Feshbach resonance by using the second-order quantum virial expansion, and point out some new features compared to the broad resonance. The interatomic interaction is modeled by the pseudopotential with an additional parameter, i.e., the effective range, to characterize the narrow-resonance width. Deep inside the width of a narrow Feshbach resonance, we find the second virial coefficient evolves with the effective range from the well-known universal value 1/41/41/4 in the broad-resonance limit to one another value 1/21/21/2 in the narrow-resonance limit. This means the Fermi gas interacts more strongly at the narrow resonance. In addition, far beyond the resonance width, we find the harmonically trapped Fermi gas still manifests an appreciable interaction effect across a narrow Feshbach resonance, which is contrary to our knowledge of the broad Feshbach resonance. All our results can be directly tested in current narrow Feshbach resonance experiments, which are generally carried out in a harmonic trap.
Unitary Fermi gases, where the scattering length is large compared to the interparticle spacing, can have universal properties, which are independent of the details of the interparticle interactions when the range of the scattering potential is negligible. We prepare an optically trapped, unitary Fermi gas of 6Li, tuned just above the center of a broad Feshbach resonance. In agreement with the universal hypothesis, we observe that this strongly interacting many-body system obeys the virial theorem for an ideal gas over a wide range of temperatures. Based on this result, we suggest a simple volume thermometry method for unitary gases. We also show that the observed breathing mode frequency, which is close to the unitary hydrodynamic value over a wide range of temperature, is consistent with a universal hydrodynamic gas with nearly isentropic dynamics.