We show that the Cerf-Adami inequalities do not necessarily depend on conditional entropies nor any reference to Markov chains. While the latter are not explicit in the original form, they are often implied in certain derivations. We also show that these inequalities are intimately related to at least one interpretation of the second law of thermodynamics. The combination of these results provides added insight into why some quantum systems violate the Cerf-Adami inequalities thereby improving our understanding of the quantum-classical boundary. As a result we suggest that the second law may serve as some type of boundary condition on classical knowledge.
We show that the Cerf-Adami inequalities do not necessarily depend on conditional entropies nor any reference to Markov chains. While the latter are not explicit in the original form, they are often implied in certain derivations. We also show that these inequalities are intimately related to at least one interpretation of the second law of thermodynamics. The combination of these results provides added insight into why some quantum systems violate the Cerf-Adami inequalities thereby improving our understanding of the quantum-classical boundary. As a result we suggest that the second law may serve as some type of boundary condition on classical knowledge.
Bell's inequalities, in the form given by Cerf and Adami, are derived from the combination of the second law of thermodynamics and the Markov postulate. Violations of these inequalities are discussed in terms of the mixing characteristics of the density operators. A quantum mechanical bound for a system of three qubits, two of which are entangled, is found and is shown to lead to strong subadditivity in one case. Finally, in interpreting the results, the role the uncertainty relations play in the definition of entropy and the second law is discussed, demonstrating a link to Bell's inequalities. Additionally the second law is shown to be dependent on the type of measurement in quantum systems. Specifically, a more general statement of the second law appropriate to both quantum and classical systems is suggested.
A colloquial interpretation of entropy is that it is the knowledge gained upon learning the outcome of a random experiment. Conditional entropy is then interpreted as the knowledge gained upon learning the outcome of one random experiment after learning the outcome of another, possibly statistically dependent, random experiment. In the classical world, entropy and conditional entropy take only non-negative values, consistent with the intuition that one has regarding the aforementioned interpretations. However, for certain entangled states, one obtains negative values when evaluating commonly accepted and information-theoretically justified formulas for the quantum conditional entropy, leading to the confounding conclusion that one can know less than nothing in the quantum world. Here, we introduce a physically motivated framework for defining quantum conditional entropy, based on two simple postulates inspired by the second law of thermodynamics (non-decrease of entropy) and extensivity of entropy, and we argue that all plausible definitions of quantum conditional entropy should respect these two postulates. We then prove that all plausible quantum conditional entropies take on negative values for certain entangled states, so that it is inevitable that one can know less than nothing in the quantum world. All of our arguments are based on constructions of physical processes that respect the first postulate, the one inspired by the second law of thermodynamics.
A consistent theory of non-equilibrium thermodynamics for Markovian open quantum systems has been developed in the late seventies in analogy with Classical Irreversible Thermodynamics. The time-evolution of these open systems is usually described by means of effective master equations in Lindblad form, that turn out to be reliable when there is a separation of time-scales between system and environment, such that memory effects are negligible and the so-called Markovian approximation is justified. In this framework, the variations of energy and entropy in the system are consistently described, distinguishing between heat and work contributions and providing a statement of the second law of thermodynamics as positivity of the entropy production.\nHowever, there is empirical evidence that many physical systems like photosynthetic complexes,\nopto-mechanical resonators and superconducting qubits, just to mention a few, experience more general non-Markovian dynamics. The formulation of the laws of thermodynamics in a non-Markovian setting is matter of current research and represents the main topic of the present work. As a first step, we show that the entropy production defined as in the Markovian case can be negative for a class of non-Markovian dynamics. We argue that this outcome should not be interpreted as a violation of the second law of thermodynamics because the environment must be explicitly taken into account in the balance of entropy in the non-Markovian setting. In order to justify this claim we adopt a more general point of view, studying a closed bipartite quantum system, such that each of the two subsystems plays the role of a finite environment out of equilibrium for the other one. We concentrate on the balance of energy first and construct an effective Hamiltonian for each subsystem using physically reasonable requirements; then we define heat and work as in the standard Markovian treatment, with the effective Hamiltonian replacing the free Hamiltonian. It turns out that, in our framework, the work power is perfectly balanced between subsystems, while the correlations can store a part of energy locally inaccessible and exchange it with both subsystems in the form of heat.\nConcerning the balance of entropy, a quite general formulation of the second law of thermodynamics can be given as follows: under the assumption of a factorized initial state for the compound system, the sum of the total variations of the entropies in the two subsystems is always nonnegative. We show with an explicit example that this general formulation does not correspond to the statement presented in the framework of Markovian master equations, which should not be considered a priori the second law of thermodynamics.\nIn the last part of the thesis we concentrate of the so-called fluctuation relations, that are results extending the thermodynamic formalism beyond the behavior of average quantities. After reviewing the main theoretical outcomes, such as the Jarzynski equality and the Crooks fluctuation theorem, we describe a proposal to access experimentally the work performed on an ensemble of diatomic molecules by a time-dependent electric field coupled with their vibrational degree of freedom. This procedure could then be used to test the quantum Jarzynski equality. With respect to the results so far appeared in the literature, in which the left-hand side of the equality is inferred from an experiment and the right-hand side is computed according to a model, in our proposed setting we should be able to estimate from the experiment both the left-hand side and the right-hand side of the equality, independently.
Thermodynamic uncertainty principles make up one of the few rare anchors in the largely uncharted waters of nonequilibrium systems, the fluctuation theorems being the more familiar. In this work we aim to trace the uncertainties of thermodynamic quantities in nonequilibrium systems to their quantum origins, namely, to the quantum uncertainty principles. Our results enable us to make this categorical statement: For Gaussian systems, thermodynamic functions are functionals of the Robertson-Schrödinger uncertainty function, which is always non-negative for quantum systems, but not necessarily so for classical systems. Here, quantum refers to noncommutativity of the canonical operator pairs. From the nonequilibrium free energy, we succeeded in deriving several inequalities between certain thermodynamic quantities. They assume the same forms as those in conventional thermodynamics, but these are nonequilibrium in nature and they hold for all times and at strong coupling. In addition we show that a fluctuation-dissipation inequality exists at all times in the nonequilibrium dynamics of the system. For nonequilibrium systems which relax to an equilibrium state at late times, this fluctuation-dissipation inequality leads to the Robertson-Schrödinger uncertainty principle with the help of the Cauchy-Schwarz inequality. This work provides the microscopic quantum basis to certain important thermodynamic properties of macroscopic nonequilibrium systems.
We consider a number of proposals for the entropy of sets of classical coarse-grained histories based on the procedures of Jaynes, and we prove a series of inequalities relating these measures. We then examine these as a function of the coarse-graining for various classical systems, and show explicitly that the entropy is minimized by the finest-grained description of a set of histories. We propose an extension of the second law of thermodynamics to the entropy of histories. We briefly discuss the implications for decoherent or consistent history formulations of quantum mechanics.