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arXiv:0712.0534 · The European Physical Journal B

Quantum thermodynamic processes: a control theory for machine cycles

J. Birjukov, T. Jahnke, G. Mahler

Published Jul 1, 2008• 33 citations
arXivHTMLPDF
DOI
10.1140/epjb/e2008-00270-2

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Thermodynamics is a theory of impressive success and a wide range of applicability. Nevertheless, it took about two hundred years after the basic formulation of phenomenological thermodynamics until Boltzmann and Maxwell gave a foundation in terms statistical mechanics based on classical mechanics. The invention of quantum mechanics has triggered various attempts to establish a theory of quantum thermodynamics, i.e., to explain and derive thermodynamics by quantum mechanics only. Recently, a new approach to this question has been developed by Gemmer et al. focusing on the role of the partitioning of the universe into "system" and "environment" and on how the entanglement between those parts and the properties of typical environments lead to a thermal state in the system for almost any instant in time. Within this approach, the emergence of thermodynamic behavior in subsystems of a wide class of autonomous quantum networks could be established although the state of the total system is a pure. This turns our understanding of the emergence of thermodynamics upside down: No longer the presence of ideal (infinitely large and always in equilibrium) makes the system thermodynamic, but thermodynamic behavior of the system itself induced by an appropriate embedding - which by itself does not need to be thermodynamic in any way - becomes the crucial ingredient. Moreover, it was found that not only macroscopic embeddings but also quantum networks as small as 10 spins may serve already as excellent thermal embeddings. In this context, this thesis approaches a number of questions: First, complementary to the emergence of relaxation (heat), how does mechanical control over a system (work) emerge in autonomous quantum systems? What types of embeddings allow for this control, and is there a lower limit of their size? The answer is discussed by making the connection between work, parametric control of a Hamiltonian, and classical driving with the help of the factorization approximation. Using this link, we propose the local effective measurement basis method to determine heat and work currents in arbitrary bipartite quantum systems, and discuss measures of how to assess the thermodynamic functionality of an arbitrary embedding. We then apply these concepts to a minimal model consisting of only a spin and a quantum harmonic oscillator (spin-oscillator model) to demonstrate that even a single oscillator may act as an ideal work reservoir. A slight variation of the model then illustrates the pros and cons of the proposed measures of thermodynamic functionality. Second, since thermodynamics is first and foremost a theory of processes, which need both, thermal and mechanical control, we ask if autonomous quantum networks can implement thermodynamic cycles. We do so by first reviewing some specialties of quantum thermodynamic processes in general and then presenting the autonomous dynamic three spin machine, an autonomous quantum network implementing a thermodynamic cycle, which is driven by a emergent quantum work reservoir as discussed in the first part. Finally, we discuss quantum thermodynamic pseudomachines, a class of models that exhibit machine-like functionality without use of a thermodynamic cycle. This gives an answer to the question how new forms of control that are only found in quantum systems lead to new thermodynamic functionalities. The presented models can all be understood as thermodynamic laser models. In particular, we discuss the extended dissipative Jaynes-Cummings model and its thermodynamic properties. We resolve a conflict between different interpretations of the model by a careful analysis of the model itself and the thermodynamic concepts used by different authors. It is found that the model is an intricate heat transport model and no machine and that its thermodynamic functionality relies on the transition-selective coupling of heat baths to a few-level quantum system.
Advances in experimental control of interacting quantum many-body systems with multiple tunable parameters-such as ultracold atomic gases and trapped ions-are driving rapid progress in quantum thermodynamics and enabling the design of quantum thermal machines. In this work, we utilize a sudden quench approximation as a means to investigate the operation of a quantum thermodynamic Otto cycle in which multiple parameters are simultaneously controllable. The method applies universally to many-body systems where such control is available, and therefore provides general principles for investigating their operation as a working medium in quantum thermal machines. We investigate application of this multi-parameter quench protocol in an experimentally realistic one-dimensional Bose gas, as well as in the transverse-field Ising model. We find that such a multi-parameter Otto cycle, when operating as an engine, outperforms not only its constituent single-parameter Otto cycles in terms of the net work and efficiency, but also the combined net work of its constituent engine cycles when added together independently. We also find that a similar multi-parameter enhancement applies to the coefficient of performance when the Otto cycle operates as a refrigerator.