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arXiv:0711.4599 · Physical Review E

Fourier’s law of heat conduction: Quantum mechanical master equation analysis

Lian-Ao Wu, Dvira Segal

Published Jun 9, 2008• 28 citations
arXivHTMLPDF

Abstract

We derive the macroscopic Fourier's Law of heat conduction from the exact gain-loss time convolutionless quantum master equation under three assumptions for the interaction kernel. To second order in the interaction, we show that the first two assumptions are natural results of the long time limit. The third assumption can be satisfied by a family of interactions consisting of an exchange effect. The pure exchange model directly leads to energy diffusion in a weakly coupled spin- 12 chain.

DOI
10.1103/physreve.77.060101

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cond-mat.mes-hallCross-listedarXiv:2609.29430•Sep 25, 2026
We derive the macroscopic Fourier's Law of heat conduction from the exact gain-loss time convolutionless quantum master equation under three assumptions for the interaction kernel. To second order in the interaction, we show that the first two assumptions are natural results of the long time limit. The third assumption can be satisfied by a family of interactions consisting of an exchange effect. The pure exchange model directly leads to energy diffusion in a weakly coupled spin- 12 chain.
We analyze closed one-dimensional chains of weakly coupled many level systems, by means of the so-called Hilbert space average method (HAM). Subject to some concrete conditions on the Hamiltonian of the system, our theory predicts energy diffusion with respect to a coarse-grained description for almost all initial states. Close to the respective equilibrium, we investigate this behavior in terms of heat transport and derive the heat conduction coefficient. Thus, we are able to show that both heat (energy) diffusive behavior as well as Fourier's law follows from and is compatible with a reversible Schrödinger dynamics on the complete level of description.
The manifestations of the three laws of thermodynamics are explored in a model of an irreversible quantum heat engine. The engine is composed of a three-level system simultaneously coupled to hot and cold heat baths, and driven by an oscillating external field. General quantum heat baths are considered, which are weakly coupled to the three-level system. The work reservoir is modeled by a classical electro-magnetic field of arbitrary intensity, which is driving the three-level system. The first law of thermodynamics is related to the rate of change of energy obtained from the quantum master equation in the Heisenberg picture. The fluxes of the thermodynamic heat and work are then directly related to the expectation values of quantum observables. An analysis of the standard quantum master equation for the amplifier, first introduced by Lamb, is shown to be thermodynamically inconsistent when strong driving fields are used. A generalized master equation is rigorously derived, starting from the underlying quantum dynamics, which includes relaxation terms that explicitly depend upon the field. For weak fields the generalized master equation reduces to the standard equation. In very intense fields the amplifier splits into two heat engines. One engine accelerates as the field intensifies, while the other slows down and eventually switches direction to become a heat pump. The relative weight of the slower engine increases with the field intensity, leading to a maximum in power as a function of the field intensity. The amplifier is shown to go through four ‘‘phases’’ as the driving field is intensified, throughout all of which the second law of thermodynamics is generally satisfied. One phase corresponds to a ‘‘refrigeration window’’ which allows for the extraction of heat out of a cold bath of temperatures down to the absolute zero. This window disappears at absolute zero, which is conjectured to be a dynamical manifestation of the third law of thermodynamics.
We investigate how the normal energy transport is realized in one-dimensional quantum systems using a quantum spin system. The direct investigation of local energy distribution under thermal gradient is made using the quantum master equation, and the mixing properties and the convergence of the Green-Kubo formula are investigated when the number of spin increases. We find that the autocorrelation function in the Green-Kubo formula decays as ∼ t −1.5 to a finite value which vanishes rapidly with the increase of the system size. As a result, the Green-Kubo formula converges to a finite value in the thermodynamic limit. These facts strongly support the realization of Fourier heat law in a quantum system.
We consider a thermal quantum harmonic oscillator weakly coupled to a heat bath at a different temperature. We analytically study the quantum heat exchange statistics between the two systems using the quantum-optical master equation. We exactly compute the characteristic function of the heat distribution and show that it verifies the Jarzynski-W\'ojcik fluctuation theorem. We further evaluate the heat probability density in the limit of long thermalization times, both in the low- and the high-temperature regimes, and investigate its time evolution by calculating its first two cumulants.
Quantum heat transport governs energy exchange processes and statistical laws in non-equilibrium quantum systems, and plays a pivotal role in quantum thermodynamics. We investigate the steady-state thermal transport of a noncommuting coupled spin system. We employ the quantum dressed master equation approach within the framework of open quantum system theory to accurately analyze the non-equilibrium dynamics, ensuring the validity of transport results in the strong coupling regime. Our results demonstrate that noncommuting spin coupling serves as a significant resource for modulating the nonlinearity of the heat current. Specifically, in the weak spin-coupling regime, the system exhibits robust negative differential thermal conductance (NDTC) across various spin numbers. By deriving analytical expressions for the heat current in both the single-spin and large-spin limits, we reveal that this NDTC behavior is governed by microscopic cycle fluxes. Physically, this arises because spin excitation channels induced by the cold reservoir are suppressed under a large temperature bias, thereby blocking energy exchange cycles. Conversely, in the strong spin-coupling and large temperature bias regime, the quantum system demonstrates pronounced thermal rectification. This high rectification efficiency originates from the unidirectional saturation of the heat current, rendering the system a promising candidate for high-performance thermal diodes. Furthermore, we extend the model to a three-terminal configuration to construct a quantum thermal transistor. By manipulating the temperature of the gate reservoir, we achieve efficient modulation and amplification of heat flow between the source and drain. The heat amplification factor is shown to far exceed unity in specific operating regions, confirming significant thermal amplification.