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arXiv:0711.3295

On Order, Disorder and Coherence

Geoffrey L. Sewell

Published Nov 21, 2007• 0 citations
arXivHTMLPDF

Abstract

We provide a brief survey of quantum statistical characterisations of order, disorder and coherence in systems of many degrees of freedom. Here, order and coherence are described in terms of symmetry breakdown, while disorder is described in terms of entropy and algorithmic complexity, whose interconnection has been recently extended from the classical to the quantum domain. We see that, in the present physical context, the concepts of order and disorder are not mutually antithetical, but bear an interrelationship similar to that between signals and noise.

DOI
10.48550/arxiv.0711.3295

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We provide a brief survey of quantum statistical characterisations of order, disorder and coherence in systems of many degrees of freedom. Here, order and coherence are described in terms of symmetry breakdown, while disorder is described in terms of entropy and algorithmic complexity, whose interconnection has been recently extended from the classical to the quantum domain. We see that, in the present physical context, the concepts of order and disorder are not mutually antithetical, but bear an interrelationship similar to that between signals and noise.
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The prevailing beliefs in the scientific and engineering literature are that: (i) thermodynamics is explained and justified by statistical mechanics; (ii) entropy is a statistical measure of disorder; and (iii) for given values of energy, volume, and amounts of constituents, the largest value of entropy corresponds to both a thermodynamic equilibrium state and the ultimate disorder. In this paper, we provide: (i) a summary of the beliefs as stated by some eminent scientists; (ii) experimental evidence that casts serious doubt about the validity of the beliefs; (iii) an outline of a nonstatistical unified quantum theory of mechanics and thermodynamics; (iv) an outline of a nonquantal, nonstatistical exposition of thermodynamics, valid for all systems (both macroscopic and microscopic), and for all states (both thermodynamic equilibrium and not thermodynamic equilibrium); (v) the definition and analytical expression of the entropy of thermodynamics; (vi) the interpretation of entropy as both a measure of the quantum-theoretic spatial shape of a molecule, and an indicator of order; and (vii) nonstatistical answers to the questions that motivated the introduction of statistical mechanics.
We study the Hamiltonian dynamics of the spherical spin model with fully-connected two-body random interactions. In the statistical physics framework, the potential energy is of the so-called p = 2 kind, closely linked to the scalar field theory. Most importantly for our setting, the energy conserving dynamics are equivalent to the ones of the Neumann integrable model. We take initial conditions from the Boltzmann equilibrium measure at a temperature that can be above or below the static phase transition, typical of a disordered (paramagnetic) or of an ordered (disguised ferromagnetic) equilibrium phase. We subsequently evolve the configurations with Newton dynamics dictated by a different Hamiltonian, obtained from an instantaneous global rescaling of the elements in the interaction random matrix. In the limit of infinitely many degrees of freedom, , we identify three dynamical phases depending on the parameters that characterise the initial state and the final Hamiltonian. We next set the analysis of the system with finite number of degrees of freedom in terms of N non-linearly coupled modes. We argue that in the limit the modes decouple at long times. We evaluate the mode temperatures and we relate them to the frequency-dependent effective temperature measured with the fluctuation-dissipation relation in the frequency domain, similarly to what was recently proposed for quantum integrable cases. Finally, we analyse the N - 1 integrals of motion, notably, their scaling with N, and we use them to show that the system is out of equilibrium in all phases, even for parameters that show an apparent Gibbs-Boltzmann behaviour of the global observables. We elaborate on the role played by these constants of motion after the quench and we briefly discuss the possible description of the asymptotic dynamics in terms of a generalised Gibbs ensemble.