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arXiv:0707.2147 · Infinite Dimensional Analysis Quantum Probability and Related Topics

GENERATORS OF DETAILED BALANCE QUANTUM MARKOV SEMIGROUPS

Franco Fagnola, Veronica Umanità

Published Sep 1, 2007• 88 citations
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Abstract

For a quantum Markov semigroup [Formula: see text] on the algebra [Formula: see text] with a faithful invariant state ρ, we can define an adjoint [Formula: see text] with respect to the scalar product determined by ρ. In this paper, we solve the open problems of characterizing adjoints [Formula: see text] that are also a quantum Markov semigroup and satisfy the detailed balance condition in terms of the operators H, Lk in the Gorini–Kossakowski–Sudarshan–Lindblad representation [Formula: see text] of the generator of [Formula: see text]. We study the adjoint semigroup with respect to both scalar products 〈a, b〉 = tr (ρa*b) and 〈a, b〉 = tr (ρ1/2a*ρ1/2 b).

DOI
10.1142/s0219025707002762

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•Jan 1, 2019•0 citations
For a quantum Markov semigroup [Formula: see text] on the algebra [Formula: see text] with a faithful invariant state ρ, we can define an adjoint [Formula: see text] with respect to the scalar product determined by ρ. In this paper, we solve the open problems of characterizing adjoints [Formula: see text] that are also a quantum Markov semigroup and satisfy the detailed balance condition in terms of the operators H, Lk in the Gorini–Kossakowski–Sudarshan–Lindblad representation [Formula: see text] of the generator of [Formula: see text]. We study the adjoint semigroup with respect to both scalar products 〈a, b〉 = tr (ρab) and 〈a, b〉 = tr (ρ1/2aρ1/2 b).
This paper explores various perspectives on Quantum Detailed Balance and the Entropy Production Rate within the framework of Quantum Markov Semigroups. Using the generators of these semigroups, formulated according to the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) theorem, and their respective adjoints, we identify two contrasting families of Quantum Markov Semigroups. The first family demonstrates a situation where the condition for Quantum Detailed Balance is violated, yet the entropy production rate is zero. In contrast, the second family reveals cases where the quantum entropy production rate aligns with an interpretation of Quantum Detailed Balance. These findings provide insights into the relationship between quantum detailed balance and entropy production rate in open systems.
Let [Formula: see text] be a quantum Markov semigroup on [Formula: see text] with a faithful normal invariant state ρ. The decoherence-free subalgebra [Formula: see text] of [Formula: see text] is the biggest subalgebra of [Formula: see text] where the completely positive maps [Formula: see text] act as homomorphisms. When [Formula: see text] is the minimal semigroup whose generator is represented in a generalised GKSL form [Formula: see text], with possibly unbounded H, Lℓ, we show that [Formula: see text] coincides with the generalised commutator of [Formula: see text] under some natural regularity conditions. As a corollary we derive simple sufficient algebraic conditions for convergence towards a steady state based on multiple commutators of H and Lℓ. We give examples of quantum Markov semigroups [Formula: see text], with h infinite-dimensional, having a non-trivial decoherence-free subalgebra.
We give an explicit entropy production formula for a class of quantum Markov semigroups, arising in the weak coupling limit of a system coupled with reservoirs, whose generators [Formula: see text] are sums of other generators [Formula: see text] associated with positive Bohr frequencies [Formula: see text] of the system. As a consequence, we show that any such semigroup satisfies the quantum detailed balance condition with respect to an invariant state if and only if all semigroups generated by each [Formula: see text] do so with respect to the same invariant state.
In recent years, digraph induced generators of quantum dynamical semigroups have been introduced and studied, particularly in the context of unique relaxation and invariance. We define the class of pair block diagonal generators, which allows for additional interaction coefficients but preserves the main structural properties. Namely, when the basis of the underlying Hilbert space is given by the eigenbasis of the Hamiltonian (for example the generic semigroups), then the action of the semigroup leaves invariant the diagonal and off-diagonal matrix spaces. In this case, we explicitly compute all invariant states of the semigroup. In order to define this class we provide a characterization of when the Gorini- Kossakowski-Sudarshan-Lindblad (GKSL) equation defines a proper generator when arbitrary Lindblad operators are allowed (in particular, they do not need to be trace- less as demanded by the GKSL Theorem). Moreover, we consider the converse con- struction to show that every generator naturally gives rise to a digraph, and that under certain assumptions the properties of this digraph can be exploited to gain knowledge of both the number and the structure of the invariant states of the corre- sponding semigroup. We also consider more general constructions on the von Neumann algebra of all bounded linear operators on a Hilbert space, perhaps infinite dimensional. In partic- ular, we prove that for every semigroup of Schwarz maps on such an algebra which has a subinvariant faithful normal state there exists an associated semigroup of con- tractions on the space of Hilbert-Schmidt operators of the Hilbert space. Moreover, we show that if the original semigroup is weak∗ continuous then the associated semigroup is strongly continuous. We introduce the notion of the extended generator of a semigroup on the bounded operators of a Hilbert space with respect to an or- thonormal basis of the Hilbert space. We describe this form of the generator of a quantum Markov semigroup on the von Neumann algebra of all bounded linear op- erators on a Hilbert space which has an invariant faithful normal state under the assumption that the generator of the associated semigroup has compact resolvent, or under the assumption that the minimal unitary dilation of the associated semigroup of contractions is compact.