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arXiv:0706.1384 · Physical Review B

Thermodynamic quantum critical behavior of the Kondo necklace model

Daniel Reyes, M. A. Contínentino

Published Aug 15, 2007• 26 citations
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Abstract

We obtain the phase diagram and thermodynamic behavior of the Kondo necklace model for arbitrary dimensions $d$ using a representation for the localized and conduction electrons in terms of local Kondo singlet and triplet operators. A decoupling scheme on the double time Green's functions yields the dispersion relation for the excitations of the system. We show that in $d\ensuremath{\geqslant}3$, there is an antiferromagnetically ordered state at finite temperatures terminating at a quantum critical point (QCP). In two dimensions, long-range magnetic order occurs only at $T=0$. The line of N\'eel transitions for $d>2$ varies with the distance to the quantum critical point QCP $\ensuremath{\mid}g\ensuremath{\mid}$ as ${T}_{N}\ensuremath{\propto}{\ensuremath{\mid}g\ensuremath{\mid}}^{\ensuremath{\psi}}$, where the shift exponent $\ensuremath{\psi}=1∕(d\ensuremath{-}1)$. In the paramagnetic side of the phase diagram, the spin gap behaves as $\ensuremath{\Delta}\ensuremath{\approx}\sqrt{\ensuremath{\mid}g\ensuremath{\mid}}$ for $d\ensuremath{\geqslant}3$, consistent with the value $z=1$ found for the dynamical critical exponent. We also find in this region a power law temperature dependence in the specific heat for ${k}_{B}T⪢\ensuremath{\Delta}$ and along the non-Fermi-liquid trajectory. For ${k}_{B}T⪡\ensuremath{\Delta}$, in the so-called Kondo spin liquid phase, the thermodynamic behavior is dominated by an exponential temperature dependence.

DOI
10.1103/physrevb.76.075114

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We obtain the phase diagram and thermodynamic behavior of the Kondo necklace model for arbitrary dimensions ddd using a representation for the localized and conduction electrons in terms of local Kondo singlet and triplet operators. A decoupling scheme on the double time Green's functions yields the dispersion relation for the excitations of the system. We show that in d\ensuremath⩾3d\ensuremath{\geqslant}3d\ensuremath⩾3, there is an antiferromagnetically ordered state at finite temperatures terminating at a quantum critical point (QCP). In two dimensions, long-range magnetic order occurs only at T=0T=0T=0. The line of N'eel transitions for d>2d>2d>2 varies with the distance to the quantum critical point QCP \ensuremath∣g\ensuremath∣\ensuremath{\mid}g\ensuremath{\mid}\ensuremath∣g\ensuremath∣ as TN\ensuremath∝\ensuremath∣g\ensuremath∣\ensuremathψ{T}_{N}\ensuremath{\propto}{\ensuremath{\mid}g\ensuremath{\mid}}^{\ensuremath{\psi}}TN​\ensuremath∝\ensuremath∣g\ensuremath∣\ensuremathψ, where the shift exponent \ensuremathψ=1∕(d\ensuremath−1)\ensuremath{\psi}=1∕(d\ensuremath{-}1)\ensuremathψ=1∕(d\ensuremath−1). In the paramagnetic side of the phase diagram, the spin gap behaves as \ensuremathΔ\ensuremath≈\ensuremath∣g\ensuremath∣\ensuremath{\Delta}\ensuremath{\approx}\sqrt{\ensuremath{\mid}g\ensuremath{\mid}}\ensuremathΔ\ensuremath≈\ensuremath∣g\ensuremath∣​ for d\ensuremath⩾3d\ensuremath{\geqslant}3d\ensuremath⩾3, consistent with the value z=1z=1z=1 found for the dynamical critical exponent. We also find in this region a power law temperature dependence in the specific heat for kBT⪢\ensuremathΔ{k}_{B}T⪢\ensuremath{\Delta}kB​T⪢\ensuremathΔ and along the non-Fermi-liquid trajectory. For kBT⪡\ensuremathΔ{k}_{B}T⪡\ensuremath{\Delta}kB​T⪡\ensuremathΔ, in the so-called Kondo spin liquid phase, the thermodynamic behavior is dominated by an exponential temperature dependence.
We have studied the quantum phase transition between the antiferromagnetic and spin liquid phases for the two-dimensional anisotropic Kondo necklace model. The bond operator formalism has been implemented to transform the spin Hamiltonian to a bosonic one. We have used the Green's function approach including a hard core repulsion to find the low energy excitation spectrum of the model. The bosonic excitations become gapless at the quantum critical point where the phase transition from the Kondo singlet state to long range antiferromagnetic order takes place. We have studied the effect of both intersite $(\ensuremath{\delta})$ and local $(\ensuremath{\Delta})$ anisotropies on the critical point and on the critical exponent of the excitation gap in the paramagnetic phase. We have also compared our results with previous bond operator mean field calculations.
We have studied the effect of anisotropies on the quantum phase transition of the Kondo necklace model in dimensions D=1D=1D=1, 2, and 3. Both the anisotropy $\ensuremath{\delta}$ of the intersite interaction term and anisotropy $\ensuremath{\Delta}$ of the on-site Kondo interaction have been included. We use a bond operator method with constraints implemented in mean-field approximation. Starting from the paramagnetic phase we determine the critical ratio (t∕J)c{(t∕J)}_{c}(t∕J)c​ of the quantum critical point and associated scaling exponents of the Kondo-singlet gap. We show that in the case of easy-axis type anisotropy $\ensuremath{\delta}>1$ a qualitatively different behavior in comparison to the conventional Kondo necklace model with $(\ensuremath{\delta},\ensuremath{\Delta})=(0,1)$ appears. We have also obtained the antiferromagnetic order parameter in the long range ordered phase for t>tct>{t}_{c}t>tc​.
We analyze several thermodynamic properties of the two-dimensional Kondo necklace using finite-temperature stochastic series expansion. In agreement with previous zero-temperature findings the model is shown to exhibit a quantum critical point (QCP), separating an antiferromagnetic from a paramagnetic dimerized state at a critical Kondo exchange-coupling strength ${J}_{c}\ensuremath{\approx}1.4$. We evaluate the temperature dependent uniform and staggered structure factors as well as the uniform and staggered susceptibilities and the local ``impurity'' susceptibility close to the QCP as well as in the ordered and quantum disordered phase. The crossover between the classical, renormalized classical, and quantum critical regime is analyzed as a function of temperature and Kondo coupling.
Abstract Using the density matrix renormalization group method, we study the one‐dimensional Kondo necklace model including two anisotropies: η in the XY interaction of the conduction chain, and Δ in the local Kondo coupling between localized and conduction spins. For different values of the anisotropies, we calculate the energy gap and estimate the quantum critical points in which a phase transition from antiferromagnetic to spin liquid states takes place, assuming a Kosterlitz–Thouless‐like behavior. For the case η=0\eta = 0η=0 , the system remains in a spin liquid state for the different Δ considered, but when η≠0\eta \ne 0η=0 , Δ markedly affects the location of the critical points. We also calculate correlation functions for a specific case, in order to support our gap results.
The Kondo-necklace model can describe magnetic low-energy limit of strongly correlated heavy fermion materials. There exist multiple energy scales in this model corresponding to each phase of the system. Here, we study quantum phase transition between the Kondo-singlet phase and the antiferromagnetic long-range ordered phase, and show the effect of anisotropies in terms of quantum information properties and vanishing energy gap. We employ the perturbative continuous unitary transformations approach to calculate the energy gap and spin-spin correlations for the model in the thermodynamic limit of one, two, and three spatial dimensions as well as for spin ladders. In particular, we show that the method, although being perturbative, can predict the expected quantum critical point, where the gap of low-energy spectrum vanishes, which is in good agreement with results of other numerical and Green's function analyses. In addition, we employ concurrence, a bipartite entanglement measure, to study the criticality of the model. Absence of singularities in the derivative of concurrence in two and three dimensions in the Kondo-necklace model shows that this model features multipartite entanglement. We also discuss crossover from the one-dimensional to the two-dimensional model via the ladder structure.
"We use the density matrix renormalization group to calculate the von Neumann block entropy in the Kondo necklace model. We have included two anisotropies: η in the exchange interaction between conduction spins, and ∆ in the coupling between localized and conduction spins. Calculating the energy gap for the one-dimensional model at zero temperature, it was obtained that when η > 0, a quantum phase transition between Kondo singlet and antiferomagnetic states for finite couplings occurs, and as ∆ increases the Kondo singlet phase is favoured. Now we observe that the quantum critical points of the model can be identified by a maximum of the von Neumann block entropy, so entanglement measures can be useful for determining the phase diagram of the anisotropic Kondo necklace model."